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Recovery and Separation of Dysprosium from Waste Neodymium Magnets through Cyphos IL 104 Extraction

In the present study, the extraction of rare earth elements (REEs) from waste neodymium magnets using phosphorus ionic liquid Cyphos IL 104 was investigated. The objective was to recover and separate the heavy REE (Dy) from light REEs (Nd and Pr). Therefore, the experimental parameters of ionic liqu...

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Autores principales: Chen, Wei-Sheng, Jian, Guo-Cai, Lee, Cheng-Han
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9369871/
https://www.ncbi.nlm.nih.gov/pubmed/35955215
http://dx.doi.org/10.3390/ma15155281
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author Chen, Wei-Sheng
Jian, Guo-Cai
Lee, Cheng-Han
author_facet Chen, Wei-Sheng
Jian, Guo-Cai
Lee, Cheng-Han
author_sort Chen, Wei-Sheng
collection PubMed
description In the present study, the extraction of rare earth elements (REEs) from waste neodymium magnets using phosphorus ionic liquid Cyphos IL 104 was investigated. The objective was to recover and separate the heavy REE (Dy) from light REEs (Nd and Pr). Therefore, the experimental parameters of ionic liquid extraction, including contacting time, the initial pH value, extractant concentration, and O/A ratio, have been optimized. The highest separation factor α(Dy/Nd) of 45.18 and α(Dy/Pr) of 47.93 has been achieved. Following the ionic liquid extraction, the comparison of different stripping agents and the stripping parameters (the concentration of stripping agent and A/O ratio) were also explored. In short terms, this research demonstrates the optimal parameters of Cyphos IL 104 for selectively extracting high REE (Dy) and reveals its potential for recovering and separating REEs in real waste.
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spelling pubmed-93698712022-08-12 Recovery and Separation of Dysprosium from Waste Neodymium Magnets through Cyphos IL 104 Extraction Chen, Wei-Sheng Jian, Guo-Cai Lee, Cheng-Han Materials (Basel) Article In the present study, the extraction of rare earth elements (REEs) from waste neodymium magnets using phosphorus ionic liquid Cyphos IL 104 was investigated. The objective was to recover and separate the heavy REE (Dy) from light REEs (Nd and Pr). Therefore, the experimental parameters of ionic liquid extraction, including contacting time, the initial pH value, extractant concentration, and O/A ratio, have been optimized. The highest separation factor α(Dy/Nd) of 45.18 and α(Dy/Pr) of 47.93 has been achieved. Following the ionic liquid extraction, the comparison of different stripping agents and the stripping parameters (the concentration of stripping agent and A/O ratio) were also explored. In short terms, this research demonstrates the optimal parameters of Cyphos IL 104 for selectively extracting high REE (Dy) and reveals its potential for recovering and separating REEs in real waste. MDPI 2022-07-30 /pmc/articles/PMC9369871/ /pubmed/35955215 http://dx.doi.org/10.3390/ma15155281 Text en © 2022 by the authors. https://creativecommons.org/licenses/by/4.0/Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/).
spellingShingle Article
Chen, Wei-Sheng
Jian, Guo-Cai
Lee, Cheng-Han
Recovery and Separation of Dysprosium from Waste Neodymium Magnets through Cyphos IL 104 Extraction
title Recovery and Separation of Dysprosium from Waste Neodymium Magnets through Cyphos IL 104 Extraction
title_full Recovery and Separation of Dysprosium from Waste Neodymium Magnets through Cyphos IL 104 Extraction
title_fullStr Recovery and Separation of Dysprosium from Waste Neodymium Magnets through Cyphos IL 104 Extraction
title_full_unstemmed Recovery and Separation of Dysprosium from Waste Neodymium Magnets through Cyphos IL 104 Extraction
title_short Recovery and Separation of Dysprosium from Waste Neodymium Magnets through Cyphos IL 104 Extraction
title_sort recovery and separation of dysprosium from waste neodymium magnets through cyphos il 104 extraction
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9369871/
https://www.ncbi.nlm.nih.gov/pubmed/35955215
http://dx.doi.org/10.3390/ma15155281
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