Electrochemical Site-Selective Alkylation of Azobenzenes with (Thio)Xanthenes

Herein, we first report an electrochemical methodology for the site-selective alkylation of azobenzenes with (thio)xanthenes in the absence of any transition metal catalyst or external oxidant. A variety of groups are compatible with this electrochemical alkylation, which furnishes the products in m...

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Detalles Bibliográficos
Autores principales: Zhong, Qiang, Gao, Hui, Wang, Pei-Long, Zhou, Chao, Miao, Tao, Li, Hongji
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2022
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9370205/
https://www.ncbi.nlm.nih.gov/pubmed/35956916
http://dx.doi.org/10.3390/molecules27154967
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author Zhong, Qiang
Gao, Hui
Wang, Pei-Long
Zhou, Chao
Miao, Tao
Li, Hongji
author_facet Zhong, Qiang
Gao, Hui
Wang, Pei-Long
Zhou, Chao
Miao, Tao
Li, Hongji
author_sort Zhong, Qiang
collection PubMed
description Herein, we first report an electrochemical methodology for the site-selective alkylation of azobenzenes with (thio)xanthenes in the absence of any transition metal catalyst or external oxidant. A variety of groups are compatible with this electrochemical alkylation, which furnishes the products in moderate to good yields.
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spelling pubmed-93702052022-08-12 Electrochemical Site-Selective Alkylation of Azobenzenes with (Thio)Xanthenes Zhong, Qiang Gao, Hui Wang, Pei-Long Zhou, Chao Miao, Tao Li, Hongji Molecules Article Herein, we first report an electrochemical methodology for the site-selective alkylation of azobenzenes with (thio)xanthenes in the absence of any transition metal catalyst or external oxidant. A variety of groups are compatible with this electrochemical alkylation, which furnishes the products in moderate to good yields. MDPI 2022-08-04 /pmc/articles/PMC9370205/ /pubmed/35956916 http://dx.doi.org/10.3390/molecules27154967 Text en © 2022 by the authors. https://creativecommons.org/licenses/by/4.0/Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/).
spellingShingle Article
Zhong, Qiang
Gao, Hui
Wang, Pei-Long
Zhou, Chao
Miao, Tao
Li, Hongji
Electrochemical Site-Selective Alkylation of Azobenzenes with (Thio)Xanthenes
title Electrochemical Site-Selective Alkylation of Azobenzenes with (Thio)Xanthenes
title_full Electrochemical Site-Selective Alkylation of Azobenzenes with (Thio)Xanthenes
title_fullStr Electrochemical Site-Selective Alkylation of Azobenzenes with (Thio)Xanthenes
title_full_unstemmed Electrochemical Site-Selective Alkylation of Azobenzenes with (Thio)Xanthenes
title_short Electrochemical Site-Selective Alkylation of Azobenzenes with (Thio)Xanthenes
title_sort electrochemical site-selective alkylation of azobenzenes with (thio)xanthenes
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9370205/
https://www.ncbi.nlm.nih.gov/pubmed/35956916
http://dx.doi.org/10.3390/molecules27154967
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AT gaohui electrochemicalsiteselectivealkylationofazobenzeneswiththioxanthenes
AT wangpeilong electrochemicalsiteselectivealkylationofazobenzeneswiththioxanthenes
AT zhouchao electrochemicalsiteselectivealkylationofazobenzeneswiththioxanthenes
AT miaotao electrochemicalsiteselectivealkylationofazobenzeneswiththioxanthenes
AT lihongji electrochemicalsiteselectivealkylationofazobenzeneswiththioxanthenes

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