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Gum Hydrocolloids Reinforced Silver Nanoparticle Sponge for Catalytic Degradation of Water Pollutants

The accumulation of organic contaminants including dyes in aquatic systems is of significant environmental concern, necessitating the development of affordable and sustainable materials for the treatment/elimination of these hazardous pollutants. Here, a green synthesis strategy has been used to dev...

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Autores principales: Ramakrishnan, Rohith K., Silvestri, Daniele, Sumitha, Nechikkottil S., Nguyen, Nhung H. A., Havlíček, Karel, Łukowiec, Dariusz, Wacławek, Stanisław, Černík, Miroslav, Tiwari, Diwakar, Padil, Vinod V. T., Varma, Rajender S.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9370489/
https://www.ncbi.nlm.nih.gov/pubmed/35956636
http://dx.doi.org/10.3390/polym14153120
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author Ramakrishnan, Rohith K.
Silvestri, Daniele
Sumitha, Nechikkottil S.
Nguyen, Nhung H. A.
Havlíček, Karel
Łukowiec, Dariusz
Wacławek, Stanisław
Černík, Miroslav
Tiwari, Diwakar
Padil, Vinod V. T.
Varma, Rajender S.
author_facet Ramakrishnan, Rohith K.
Silvestri, Daniele
Sumitha, Nechikkottil S.
Nguyen, Nhung H. A.
Havlíček, Karel
Łukowiec, Dariusz
Wacławek, Stanisław
Černík, Miroslav
Tiwari, Diwakar
Padil, Vinod V. T.
Varma, Rajender S.
author_sort Ramakrishnan, Rohith K.
collection PubMed
description The accumulation of organic contaminants including dyes in aquatic systems is of significant environmental concern, necessitating the development of affordable and sustainable materials for the treatment/elimination of these hazardous pollutants. Here, a green synthesis strategy has been used to develop a self-assembled gum kondagogu-sodium alginate bioconjugate sponge adorned with silver nanoparticles, for the first time. The properties of the nanocomposite sponge were then analyzed using FTIR, TGA, SEM, and MicroCT. The ensued biobased sponge exhibited hierarchical microstructure, open cellular pores, good shape memory, and mechanical properties. It merges the attributes of an open cellular porous structure with metal nanoparticles and are envisaged to be deployed as a sustainable catalytic system for reducing contaminants in the aqueous environment. This nanocomposite sponge showed enhanced catalytic effectiveness (k(m) values up to 37 min(−1) g(−1) and 44 min(−1) g(−1) for methylene blue and 4-nitrophenol, respectively), antibacterial properties, reusability, and biodegradability (65% biodegradation in 28 days).
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spelling pubmed-93704892022-08-12 Gum Hydrocolloids Reinforced Silver Nanoparticle Sponge for Catalytic Degradation of Water Pollutants Ramakrishnan, Rohith K. Silvestri, Daniele Sumitha, Nechikkottil S. Nguyen, Nhung H. A. Havlíček, Karel Łukowiec, Dariusz Wacławek, Stanisław Černík, Miroslav Tiwari, Diwakar Padil, Vinod V. T. Varma, Rajender S. Polymers (Basel) Article The accumulation of organic contaminants including dyes in aquatic systems is of significant environmental concern, necessitating the development of affordable and sustainable materials for the treatment/elimination of these hazardous pollutants. Here, a green synthesis strategy has been used to develop a self-assembled gum kondagogu-sodium alginate bioconjugate sponge adorned with silver nanoparticles, for the first time. The properties of the nanocomposite sponge were then analyzed using FTIR, TGA, SEM, and MicroCT. The ensued biobased sponge exhibited hierarchical microstructure, open cellular pores, good shape memory, and mechanical properties. It merges the attributes of an open cellular porous structure with metal nanoparticles and are envisaged to be deployed as a sustainable catalytic system for reducing contaminants in the aqueous environment. This nanocomposite sponge showed enhanced catalytic effectiveness (k(m) values up to 37 min(−1) g(−1) and 44 min(−1) g(−1) for methylene blue and 4-nitrophenol, respectively), antibacterial properties, reusability, and biodegradability (65% biodegradation in 28 days). MDPI 2022-07-31 /pmc/articles/PMC9370489/ /pubmed/35956636 http://dx.doi.org/10.3390/polym14153120 Text en © 2022 by the authors. https://creativecommons.org/licenses/by/4.0/Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/).
spellingShingle Article
Ramakrishnan, Rohith K.
Silvestri, Daniele
Sumitha, Nechikkottil S.
Nguyen, Nhung H. A.
Havlíček, Karel
Łukowiec, Dariusz
Wacławek, Stanisław
Černík, Miroslav
Tiwari, Diwakar
Padil, Vinod V. T.
Varma, Rajender S.
Gum Hydrocolloids Reinforced Silver Nanoparticle Sponge for Catalytic Degradation of Water Pollutants
title Gum Hydrocolloids Reinforced Silver Nanoparticle Sponge for Catalytic Degradation of Water Pollutants
title_full Gum Hydrocolloids Reinforced Silver Nanoparticle Sponge for Catalytic Degradation of Water Pollutants
title_fullStr Gum Hydrocolloids Reinforced Silver Nanoparticle Sponge for Catalytic Degradation of Water Pollutants
title_full_unstemmed Gum Hydrocolloids Reinforced Silver Nanoparticle Sponge for Catalytic Degradation of Water Pollutants
title_short Gum Hydrocolloids Reinforced Silver Nanoparticle Sponge for Catalytic Degradation of Water Pollutants
title_sort gum hydrocolloids reinforced silver nanoparticle sponge for catalytic degradation of water pollutants
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9370489/
https://www.ncbi.nlm.nih.gov/pubmed/35956636
http://dx.doi.org/10.3390/polym14153120
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