Combination of Micelle Collapse and CuNi Surface Dissolution for Electrodeposition of Magnetic Freestanding Chitosan Film

Magnetic chitosan hydrogel has aroused immense attention in recent years due to their biomedical significance and magnetic responsiveness. Here, A new electrodeposition method is reported for the fabrication of a novel CuNi-based magnetic chitosan freestanding film (MCFF) in an acidic chitosan plating bath containing SDS-modified CuNi NPs. Contrary to chitosan’s anodic and cathodic deposition, which typically involves electrochemical oxidation, the synthetic process is triggered by coordination of chitosan with Cu and Ni ions in situ generated by the controlled surface dissolution of the suspended NPs with the acidic plating bath. The NPs provide not only the ions required for chitosan growth but also become entrapped during electrodeposition, thereby endowing the composite with magnetic properties. The obtained MCFF offers a wide range of features, including good mechanical strength, magnetic properties, homogeneity, and morphological transparency. Besides the fundamental interest of the synthesis itself, sufficient mechanical strength ensures that the hydrogel can be used by either peeling it off of the electrode or by directly building a complex hydrogel electrode. Its fast and easy magnetic steering, separation and recovery, large surface area, lack of secondary pollution, and strong chelating capability could lead to it finding applications as an electrochemical detector or adsorbent.