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Tip-Enhanced Raman Spectroscopy Based on Spiral Plasmonic Lens Excitation

In this study, we proposed the idea of replacing the traditional objective lens in bottom-illumination mode with a plasmonic lens (PL) to achieve tip-enhanced Raman spectroscopy (TERS). The electric field energy of surface plasmon polaritons (SPPs) of the spiral PL was found to be more concentrated...

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Detalles Bibliográficos
Autores principales: Gu, Kai, Sun, Ming, Zhang, Yang
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9371167/
https://www.ncbi.nlm.nih.gov/pubmed/35957194
http://dx.doi.org/10.3390/s22155636
Descripción
Sumario:In this study, we proposed the idea of replacing the traditional objective lens in bottom-illumination mode with a plasmonic lens (PL) to achieve tip-enhanced Raman spectroscopy (TERS). The electric field energy of surface plasmon polaritons (SPPs) of the spiral PL was found to be more concentrated at the focal point without any sidelobe using the finite-difference time domain (FDTD) method compared with that of a symmetry-breaking PL. This property reduces far-field background noise and increases the excitation efficiency of the near-field Raman signal. The disadvantage of only the near-field Raman scattering of samples at the center of the structure being detected when using an ordinary PL in TERS is overcome by using our proposed method of changing only the polarization of the incident light.