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Double universality of the transition in the supercritical state
Universality aids consistent understanding of physical properties and states of matter where a theory predicts how a property of a phase (solid, liquid, and gas) changes with temperature or pressure. Here, we show that the matter above the critical point has a remarkable double universality. The fir...
Autores principales: | , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
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American Association for the Advancement of Science
2022
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9374332/ https://www.ncbi.nlm.nih.gov/pubmed/35960792 http://dx.doi.org/10.1126/sciadv.abq5183 |
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author | Cockrell, Cillian Trachenko, Kostya |
author_facet | Cockrell, Cillian Trachenko, Kostya |
author_sort | Cockrell, Cillian |
collection | PubMed |
description | Universality aids consistent understanding of physical properties and states of matter where a theory predicts how a property of a phase (solid, liquid, and gas) changes with temperature or pressure. Here, we show that the matter above the critical point has a remarkable double universality. The first universality is the transition between the liquid-like and gas-like states seen in the crossover of the specific heat on the dynamical length with a fixed inversion point. The second universality is the operation of this effect in many supercritical fluids, including N(2), CO(2), Pb, H(2)O, and Ar. Despite different structure and chemical bonding, the transition has the same fixed inversion point deep in the supercritical state. This advances our understanding of the supercritical state previously considered to be a featureless area on the phase diagram and a theoretical guide for improved deployment of supercritical fluids in green and environmental applications. |
format | Online Article Text |
id | pubmed-9374332 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2022 |
publisher | American Association for the Advancement of Science |
record_format | MEDLINE/PubMed |
spelling | pubmed-93743322022-08-18 Double universality of the transition in the supercritical state Cockrell, Cillian Trachenko, Kostya Sci Adv Physical and Materials Sciences Universality aids consistent understanding of physical properties and states of matter where a theory predicts how a property of a phase (solid, liquid, and gas) changes with temperature or pressure. Here, we show that the matter above the critical point has a remarkable double universality. The first universality is the transition between the liquid-like and gas-like states seen in the crossover of the specific heat on the dynamical length with a fixed inversion point. The second universality is the operation of this effect in many supercritical fluids, including N(2), CO(2), Pb, H(2)O, and Ar. Despite different structure and chemical bonding, the transition has the same fixed inversion point deep in the supercritical state. This advances our understanding of the supercritical state previously considered to be a featureless area on the phase diagram and a theoretical guide for improved deployment of supercritical fluids in green and environmental applications. American Association for the Advancement of Science 2022-08-12 /pmc/articles/PMC9374332/ /pubmed/35960792 http://dx.doi.org/10.1126/sciadv.abq5183 Text en Copyright © 2022 The Authors, some rights reserved; exclusive licensee American Association for the Advancement of Science. No claim to original U.S. Government Works. Distributed under a Creative Commons Attribution NonCommercial License 4.0 (CC BY-NC). https://creativecommons.org/licenses/by-nc/4.0/This is an open-access article distributed under the terms of the Creative Commons Attribution-NonCommercial license (https://creativecommons.org/licenses/by-nc/4.0/) , which permits use, distribution, and reproduction in any medium, so long as the resultant use is not for commercial advantage and provided the original work is properly cited. |
spellingShingle | Physical and Materials Sciences Cockrell, Cillian Trachenko, Kostya Double universality of the transition in the supercritical state |
title | Double universality of the transition in the supercritical state |
title_full | Double universality of the transition in the supercritical state |
title_fullStr | Double universality of the transition in the supercritical state |
title_full_unstemmed | Double universality of the transition in the supercritical state |
title_short | Double universality of the transition in the supercritical state |
title_sort | double universality of the transition in the supercritical state |
topic | Physical and Materials Sciences |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9374332/ https://www.ncbi.nlm.nih.gov/pubmed/35960792 http://dx.doi.org/10.1126/sciadv.abq5183 |
work_keys_str_mv | AT cockrellcillian doubleuniversalityofthetransitioninthesupercriticalstate AT trachenkokostya doubleuniversalityofthetransitioninthesupercriticalstate |