Diastereoselective Radical 1,4-Ester Migration: Radical Cyclizations of Acyclic Esters with SmI(2)

[Image: see text] Reductive cyclizations of carbonyl compounds, mediated by samarium(II) diiodide (SmI(2), Kagan’s reagent), represent an invaluable platform to generate molecular complexity in a stereocontrolled manner. In addition to classical ketone and aldehyde substrates, recent advances in rad...

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Detalles Bibliográficos
Autores principales: Morrill, Charlotte, Péter, Áron, Amalina, Ilma, Pye, Emma, Crisenza, Giacomo E. M., Kaltsoyannis, Nikolas, Procter, David J.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2022
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9377304/
https://www.ncbi.nlm.nih.gov/pubmed/35858251
http://dx.doi.org/10.1021/jacs.2c05972

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9377304/
https://www.ncbi.nlm.nih.gov/pubmed/35858251
http://dx.doi.org/10.1021/jacs.2c05972

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