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Diastereoselective Radical 1,4-Ester Migration: Radical Cyclizations of Acyclic Esters with SmI(2)
[Image: see text] Reductive cyclizations of carbonyl compounds, mediated by samarium(II) diiodide (SmI(2), Kagan’s reagent), represent an invaluable platform to generate molecular complexity in a stereocontrolled manner. In addition to classical ketone and aldehyde substrates, recent advances in rad...
| Autores principales: | , , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical Society
2022
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9377304/ https://www.ncbi.nlm.nih.gov/pubmed/35858251 http://dx.doi.org/10.1021/jacs.2c05972 |