Cargando…

Phosphorescent Tris-cyclometalated Pt(IV) Complexes with Mesoionic N-Heterocyclic Carbene and 2-Arylpyridine Ligands

[Image: see text] The synthesis, structure, photophysical properties, and electrochemistry of the first series of Pt(IV) tris-chelates bearing cyclometalated aryl-NHC ligands are reported. The complexes have the general formula [Pt(trz)(2)(C∧N)](+), combining two units of the cyclometalated, mesoion...

Descripción completa

Detalles Bibliográficos
Autores principales:	Vivancos, Ángela, Bautista, Delia, González-Herrero, Pablo
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	American Chemical Society 2022
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9377419/ https://www.ncbi.nlm.nih.gov/pubmed/35860839 http://dx.doi.org/10.1021/acs.inorgchem.2c02039

Ejemplares similares

Strongly Luminescent Pt(IV) Complexes with a Mesoionic N-Heterocyclic Carbene Ligand: Tuning Their Photophysical Properties
por: Vivancos, Ángela, et al.
Publicado: (2021)

Visible light driven generation and alkyne insertion reactions of stable bis-cyclometalated Pt(iv) hydrides
por: Poveda, Dionisio, et al.
Publicado: (2020)

Mesoionic Carbene Complexes of Uranium(IV) and Thorium(IV)
por: Seed, John A., et al.
Publicado: (2022)

Photoinduced Reductive C–C and C–Heteroatom Couplings from Bis-cyclometalated Pt(IV) Alkynyl Complexes
por: López-López, Juan Carlos, et al.
Publicado: (2023)

Photochemically Induced Cyclometalations at Simple Platinum(II) Precursors
por: Poveda, Dionisio, et al.
Publicado: (2023)

The Core Difference between a Mesoionic and a Normal N-Heterocyclic Carbene
por: Barnett, Christopher, et al.
Publicado: (2022)

Ferrous and ferric complexes with cyclometalating N-heterocyclic carbene ligands: a case of dual emission revisited
por: Johnson, Catherine Ellen, et al.
Publicado: (2023)

Sydnone Methides—A Forgotten Class of Mesoionic Compounds for the Generation of Anionic N‐Heterocyclic Carbenes
por: Mummel, Sebastian, et al.
Publicado: (2021)

Rare‐Earth‐ and Uranium‐Mesoionic Carbenes: A New Class of f‐Block Carbene Complex Derived from an N‐Heterocyclic Olefin
por: Seed, John A., et al.
Publicado: (2017)

Stabilization of Boron–Boron Triple Bonds by Mesoionic Carbenes
por: Saha, Ranajit, et al.
Publicado: (2018)

Mesoionic Carbenes in Low- to High-Valent Vanadium Chemistry
por: Neururer, Florian R., et al.
Publicado: (2021)

Complementing Pyridine‐2,6‐bis(oxazoline) with Cyclometalated N‐Heterocyclic Carbene for Asymmetric Ruthenium Catalysis
por: Li, Long, et al.
Publicado: (2020)

Stable Mesoionic N‐Heterocyclic Olefins (mNHOs)
por: Hansmann, Max M., et al.
Publicado: (2020)

Theoretical perspective on the electronic structure and photophysical properties for a series of mixed-carbene tris-cyclometalated iridium(iii) complexes
por: Li, Jiawei, et al.
Publicado: (2020)

N-Heterocyclic Carbene Platinum(IV) as Metallodrug Candidates: Synthesis and (195)Pt NMR Chemical Shift Trend
por: Bouché, Mathilde, et al.
Publicado: (2020)

Cobaltocenylidene: A Mesoionic Metalloceno Carbene, Stabilized in a Gold(III) Complex
por: Vanicek, Stefan, et al.
Publicado: (2018)

Copper(I) Complexes of Mesoionic Carbene: Structural Characterization and Catalytic Hydrosilylation Reactions
por: Hohloch, Stephan, et al.
Publicado: (2015)

Chemistry of Compounds Based on 1,2,3-Triazolylidene-Type Mesoionic Carbenes
por: Maity, Ramananda, et al.
Publicado: (2021)

Impact of Bidentate Pyridyl-Mesoionic Carbene Ligands: Structural, (Spectro)Electrochemical, Photophysical, and Theoretical Investigations on Ruthenium(II) Complexes
por: Bens, Tobias, et al.
Publicado: (2023)

Functionalised N‐Heterocyclic Carbene Ligands in Bimetallic Architectures
por: Evans, Kieren J., et al.
Publicado: (2020)

Mixed-carbene cyclometalated iridium complexes with saturated blue luminescence
por: Na, Hanah, et al.
Publicado: (2019)

Phosphorescent cyclometalated complexes for efficient blue organic light-emitting diodes
por: Suzuri, Yoshiyuki, et al.
Publicado: (2014)

An Efficient Probe of Cyclometallated Phosphorescent Iridium Complex for Selective Detection of Cyanide
por: Lin, Nan, et al.
Publicado: (2020)

Nickel‐Catalyzed Intramolecular 1,2‐Aryl Migration of Mesoionic Carbenes (iMICs)
por: Merschel, Arne, et al.
Publicado: (2020)

Tuning the π‐Accepting Properties of Mesoionic Carbenes: A Combined Computational and Experimental Study
por: Dong, Zhaowen, et al.
Publicado: (2021)

The Exchange of Cyclometalated Ligands
por: Ryabov, Alexander D.
Publicado: (2021)

Methylpalladium complexes with pyrimidine-functionalized N-heterocyclic carbene ligands
por: Meyer, Dirk, et al.
Publicado: (2016)

Carbenaporphyrins: No Longer Missing Ligands in N‐Heterocyclic Carbene Chemistry
por: Maulbetsch, Theo, et al.
Publicado: (2020)

Tuning the Photophysical Properties of Homoleptic Tris-Cyclometalated Ir(III) Complexes by Facile Modification of the Imidazo-Phenanthridine and Their Application to Phosphorescent Organic Light-Emitting Diodes
por: Kim, So-Yoen, et al.
Publicado: (2022)

N-Heterocyclic carbenes
por: Nolan, Steven P
Publicado: (2015)

N‐Heterocyclic Carbene Organocatalysis: With or Without Carbenes?
por: Gehrke, Sascha, et al.
Publicado: (2020)

Phosphorescent Imaging of Living Cells Using a Cyclometalated Iridium(III) Complex
por: Ma, Dik-Lung, et al.
Publicado: (2013)

Palladium Mesoionic Carbene Pre-catalyst for General Cross-Coupling Transformations in Deep Eutectic Solvents
por: Marset, Xavier, et al.
Publicado: (2019)

A theoretical study on the on–off phosphorescence of novel Pt(ii)/Pt(iv)–bisphenylpyridinylmethane complexes
por: Zhu, Guoxun, et al.
Publicado: (2022)

Harnessing asymmetric N-heterocyclic carbene ligands to optimise SABRE hyperpolarisation
por: Wong, Chin Min, et al.
Publicado: (2018)

Anticancer Gold(III) Compounds With Porphyrin or N-heterocyclic Carbene Ligands
por: Tong, Ka-Chung, et al.
Publicado: (2020)

Recent Advances in Catalysis Involving Bidentate N-Heterocyclic Carbene Ligands
por: Neshat, Abdollah, et al.
Publicado: (2021)

N-Heterocyclic Carbene Ligand Stability on Gold Nanoparticles in Biological Media
por: Sherman, Lindy M., et al.
Publicado: (2021)

Targeting cancer cell metabolism with mitochondria-immobilized phosphorescent cyclometalated iridium(iii) complexes
por: Cao, Jian-Jun, et al.
Publicado: (2017)

Polymorphism and Mechanochromism in 2-Phenylbenzothiazole Cyclometalated Pt(II) Complexes with Chelating N(∧)O Ligands
por: Gómez de Segura, David, et al.
Publicado: (2022)

Cannot write session to /tmp/vufind_sessions/sess_ag7ecncv4fmq0923vlili5d0n8