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The transient-chelating-group-controlled stereoselective Rh(i)-catalyzed silylative aminocarbonylation of 2-alkynylanilines: access to (Z)-3-(silylmethylene)indolin-2-ones

A new method involving mild acryl transient-chelating-group-controlled stereoselective Rh(i)-catalyzed silylative aminocarbonylation of 2-alkynylanilines with CO and silanes is presented for producing (Z)-3-(silylmethylene)indolin-2-ones. Upon using an acryl transient chelating group, 2-alkynylanili...

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Detalles Bibliográficos
Autores principales:	Han, Ya-Fei, Lv, Gui-Fen, Li, Yang, Wu, Li-Jun, Ouyang, Xuan-Hui, Li, Jin-Heng
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	The Royal Society of Chemistry 2022
Materias:	Chemistry
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9383873/ https://www.ncbi.nlm.nih.gov/pubmed/36092994 http://dx.doi.org/10.1039/d2sc03009h

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