Torsionally broken symmetry assists infrared excitation of biomimetic charge-coupled nuclear motions in the electronic ground state

The concerted interplay between reactive nuclear and electronic motions in molecules actuates chemistry. Here, we demonstrate that out-of-plane torsional deformation and vibrational excitation of stretching motions in the electronic ground state modulate the charge-density distribution in a donor-br...

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Detalles Bibliográficos
Autores principales: Chatterjee, Gourab, Jha, Ajay, Blanco-Gonzalez, Alejandro, Tiwari, Vandana, Manathunga, Madushanka, Duan, Hong-Guang, Tellkamp, Friedjof, Prokhorenko, Valentyn I., Ferré, Nicolas, Dasgupta, Jyotishman, Olivucci, Massimo, Miller, R. J. Dwayne
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2022
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9384489/
https://www.ncbi.nlm.nih.gov/pubmed/36093002
http://dx.doi.org/10.1039/d2sc02133a

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9384489/
https://www.ncbi.nlm.nih.gov/pubmed/36093002
http://dx.doi.org/10.1039/d2sc02133a

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