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(NH(4))(3)B(11)PO(19)F(3): a deep-UV nonlinear optical crystal with unique [B(5)PO(10)F](∞) layers
Deep-ultraviolet (DUV) nonlinear optical (NLO) crystals that can extend the output range of coherent light below 200 nm are pivotal materials for solid-state lasers. To date, KBe(2)BO(3)F(2) (KBBF) is the only usable crystal that can generate DUV coherent light by direct second harmonic generation (...
Autores principales: | , , , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Oxford University Press
2022
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9385455/ https://www.ncbi.nlm.nih.gov/pubmed/35992234 http://dx.doi.org/10.1093/nsr/nwac110 |
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author | Cheng, Bingliang Li, Zijian Chu, Yu Tudi, Abudukadi Mutailipu, Miriding Zhang, Fangfang Yang, Zhihua Pan, Shilie |
author_facet | Cheng, Bingliang Li, Zijian Chu, Yu Tudi, Abudukadi Mutailipu, Miriding Zhang, Fangfang Yang, Zhihua Pan, Shilie |
author_sort | Cheng, Bingliang |
collection | PubMed |
description | Deep-ultraviolet (DUV) nonlinear optical (NLO) crystals that can extend the output range of coherent light below 200 nm are pivotal materials for solid-state lasers. To date, KBe(2)BO(3)F(2) (KBBF) is the only usable crystal that can generate DUV coherent light by direct second harmonic generation (SHG), but the layered growth habit and toxic ingredients limit its application. Herein, we report a new fluoroborophosphate, (NH(4))(3)B(11)PO(19)F(3) (ABPF), containing four different functional units: [BO(3)], [BO(4)], [BO(3)F] and [PO(4)]. ABPF exhibits a KBBF-like structure while eliminating the limitations of KBBF crystal. The unique [B(5)PO(10)F](∞) layers enhance ABPF’s performance; for example, it has a large SHG response (1.2 × KDP) and a sufficient birefringence (0.088 at 1064 nm) that enables the shortest phase-matching wavelength to reach the DUV region. Meanwhile, the introduction of strong B-O-P covalent bonds decreases the layered growth habit. These findings will enrich the structural chemistry of fluoroborophosphate and contribute to the discovery of more excellent DUV NLO crystals. |
format | Online Article Text |
id | pubmed-9385455 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2022 |
publisher | Oxford University Press |
record_format | MEDLINE/PubMed |
spelling | pubmed-93854552022-08-18 (NH(4))(3)B(11)PO(19)F(3): a deep-UV nonlinear optical crystal with unique [B(5)PO(10)F](∞) layers Cheng, Bingliang Li, Zijian Chu, Yu Tudi, Abudukadi Mutailipu, Miriding Zhang, Fangfang Yang, Zhihua Pan, Shilie Natl Sci Rev Research Article Deep-ultraviolet (DUV) nonlinear optical (NLO) crystals that can extend the output range of coherent light below 200 nm are pivotal materials for solid-state lasers. To date, KBe(2)BO(3)F(2) (KBBF) is the only usable crystal that can generate DUV coherent light by direct second harmonic generation (SHG), but the layered growth habit and toxic ingredients limit its application. Herein, we report a new fluoroborophosphate, (NH(4))(3)B(11)PO(19)F(3) (ABPF), containing four different functional units: [BO(3)], [BO(4)], [BO(3)F] and [PO(4)]. ABPF exhibits a KBBF-like structure while eliminating the limitations of KBBF crystal. The unique [B(5)PO(10)F](∞) layers enhance ABPF’s performance; for example, it has a large SHG response (1.2 × KDP) and a sufficient birefringence (0.088 at 1064 nm) that enables the shortest phase-matching wavelength to reach the DUV region. Meanwhile, the introduction of strong B-O-P covalent bonds decreases the layered growth habit. These findings will enrich the structural chemistry of fluoroborophosphate and contribute to the discovery of more excellent DUV NLO crystals. Oxford University Press 2022-06-10 /pmc/articles/PMC9385455/ /pubmed/35992234 http://dx.doi.org/10.1093/nsr/nwac110 Text en © The Author(s) 2022. Published by Oxford University Press on behalf of China Science Publishing & Media Ltd. https://creativecommons.org/licenses/by/4.0/This is an Open Access article distributed under the terms of the Creative Commons Attribution License (https://creativecommons.org/licenses/by/4.0/), which permits unrestricted reuse, distribution, and reproduction in any medium, provided the original work is properly cited. |
spellingShingle | Research Article Cheng, Bingliang Li, Zijian Chu, Yu Tudi, Abudukadi Mutailipu, Miriding Zhang, Fangfang Yang, Zhihua Pan, Shilie (NH(4))(3)B(11)PO(19)F(3): a deep-UV nonlinear optical crystal with unique [B(5)PO(10)F](∞) layers |
title | (NH(4))(3)B(11)PO(19)F(3): a deep-UV nonlinear optical crystal with unique [B(5)PO(10)F](∞) layers |
title_full | (NH(4))(3)B(11)PO(19)F(3): a deep-UV nonlinear optical crystal with unique [B(5)PO(10)F](∞) layers |
title_fullStr | (NH(4))(3)B(11)PO(19)F(3): a deep-UV nonlinear optical crystal with unique [B(5)PO(10)F](∞) layers |
title_full_unstemmed | (NH(4))(3)B(11)PO(19)F(3): a deep-UV nonlinear optical crystal with unique [B(5)PO(10)F](∞) layers |
title_short | (NH(4))(3)B(11)PO(19)F(3): a deep-UV nonlinear optical crystal with unique [B(5)PO(10)F](∞) layers |
title_sort | (nh(4))(3)b(11)po(19)f(3): a deep-uv nonlinear optical crystal with unique [b(5)po(10)f](∞) layers |
topic | Research Article |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9385455/ https://www.ncbi.nlm.nih.gov/pubmed/35992234 http://dx.doi.org/10.1093/nsr/nwac110 |
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