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Study on NO Removal Characteristics of the Fe(II)EDTA and Fe(II)PBTCA Composite System
[Image: see text] Fe(2+) complexation wet denitrification technology has become a research hotspot. It is very important to achieve efficient regeneration of the absorbent and increase NO absorption in the Fe(2+) complexation system. They are the key to the industrial application of the Fe(2+) compl...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
American Chemical Society
2022
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9386696/ https://www.ncbi.nlm.nih.gov/pubmed/35990463 http://dx.doi.org/10.1021/acsomega.2c01641 |
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author | Ma, Liwei Li, Guoqiang Wang, Youqian Chai, Siqi Zhang, Guojie |
author_facet | Ma, Liwei Li, Guoqiang Wang, Youqian Chai, Siqi Zhang, Guojie |
author_sort | Ma, Liwei |
collection | PubMed |
description | [Image: see text] Fe(2+) complexation wet denitrification technology has become a research hotspot. It is very important to achieve efficient regeneration of the absorbent and increase NO absorption in the Fe(2+) complexation system. They are the key to the industrial application of the Fe(2+) complexation absorption process. In this paper, 2-phosphonate-butane-1,2,4-tricarboxylic acid and ethylenediamine tetraacetic acid were used as ligands to prepare a composite system for the first time. The characteristics of NO removal were investigated under different temperatures, pHs, Fe(2+) concentrations, O(2) contents, NO concentrations, CO(2) contents, and SO(2) concentrations. Compared with the single ligand, the results show that the denitrification performance of the solution with a complex ligand is significantly improved. In this system, pH 9, 40 °C temperature, and 20 mmol/L Fe(2+) concentration are the economic ideal conditions for NO removal. The system can realize simultaneous removal of NO and SO(2), but SO(2) in flue gas has a dual effect on the NO removal reaction. |
format | Online Article Text |
id | pubmed-9386696 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2022 |
publisher | American Chemical Society |
record_format | MEDLINE/PubMed |
spelling | pubmed-93866962022-08-19 Study on NO Removal Characteristics of the Fe(II)EDTA and Fe(II)PBTCA Composite System Ma, Liwei Li, Guoqiang Wang, Youqian Chai, Siqi Zhang, Guojie ACS Omega [Image: see text] Fe(2+) complexation wet denitrification technology has become a research hotspot. It is very important to achieve efficient regeneration of the absorbent and increase NO absorption in the Fe(2+) complexation system. They are the key to the industrial application of the Fe(2+) complexation absorption process. In this paper, 2-phosphonate-butane-1,2,4-tricarboxylic acid and ethylenediamine tetraacetic acid were used as ligands to prepare a composite system for the first time. The characteristics of NO removal were investigated under different temperatures, pHs, Fe(2+) concentrations, O(2) contents, NO concentrations, CO(2) contents, and SO(2) concentrations. Compared with the single ligand, the results show that the denitrification performance of the solution with a complex ligand is significantly improved. In this system, pH 9, 40 °C temperature, and 20 mmol/L Fe(2+) concentration are the economic ideal conditions for NO removal. The system can realize simultaneous removal of NO and SO(2), but SO(2) in flue gas has a dual effect on the NO removal reaction. American Chemical Society 2022-08-08 /pmc/articles/PMC9386696/ /pubmed/35990463 http://dx.doi.org/10.1021/acsomega.2c01641 Text en © 2022 The Authors. Published by American Chemical Society https://creativecommons.org/licenses/by-nc-nd/4.0/Permits non-commercial access and re-use, provided that author attribution and integrity are maintained; but does not permit creation of adaptations or other derivative works (https://creativecommons.org/licenses/by-nc-nd/4.0/). |
spellingShingle | Ma, Liwei Li, Guoqiang Wang, Youqian Chai, Siqi Zhang, Guojie Study on NO Removal Characteristics of the Fe(II)EDTA and Fe(II)PBTCA Composite System |
title | Study on NO Removal
Characteristics of the Fe(II)EDTA
and Fe(II)PBTCA Composite System |
title_full | Study on NO Removal
Characteristics of the Fe(II)EDTA
and Fe(II)PBTCA Composite System |
title_fullStr | Study on NO Removal
Characteristics of the Fe(II)EDTA
and Fe(II)PBTCA Composite System |
title_full_unstemmed | Study on NO Removal
Characteristics of the Fe(II)EDTA
and Fe(II)PBTCA Composite System |
title_short | Study on NO Removal
Characteristics of the Fe(II)EDTA
and Fe(II)PBTCA Composite System |
title_sort | study on no removal
characteristics of the fe(ii)edta
and fe(ii)pbtca composite system |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9386696/ https://www.ncbi.nlm.nih.gov/pubmed/35990463 http://dx.doi.org/10.1021/acsomega.2c01641 |
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