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Study on NO Removal Characteristics of the Fe(II)EDTA and Fe(II)PBTCA Composite System

[Image: see text] Fe(2+) complexation wet denitrification technology has become a research hotspot. It is very important to achieve efficient regeneration of the absorbent and increase NO absorption in the Fe(2+) complexation system. They are the key to the industrial application of the Fe(2+) compl...

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Autores principales: Ma, Liwei, Li, Guoqiang, Wang, Youqian, Chai, Siqi, Zhang, Guojie
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2022
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9386696/
https://www.ncbi.nlm.nih.gov/pubmed/35990463
http://dx.doi.org/10.1021/acsomega.2c01641
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author Ma, Liwei
Li, Guoqiang
Wang, Youqian
Chai, Siqi
Zhang, Guojie
author_facet Ma, Liwei
Li, Guoqiang
Wang, Youqian
Chai, Siqi
Zhang, Guojie
author_sort Ma, Liwei
collection PubMed
description [Image: see text] Fe(2+) complexation wet denitrification technology has become a research hotspot. It is very important to achieve efficient regeneration of the absorbent and increase NO absorption in the Fe(2+) complexation system. They are the key to the industrial application of the Fe(2+) complexation absorption process. In this paper, 2-phosphonate-butane-1,2,4-tricarboxylic acid and ethylenediamine tetraacetic acid were used as ligands to prepare a composite system for the first time. The characteristics of NO removal were investigated under different temperatures, pHs, Fe(2+) concentrations, O(2) contents, NO concentrations, CO(2) contents, and SO(2) concentrations. Compared with the single ligand, the results show that the denitrification performance of the solution with a complex ligand is significantly improved. In this system, pH 9, 40 °C temperature, and 20 mmol/L Fe(2+) concentration are the economic ideal conditions for NO removal. The system can realize simultaneous removal of NO and SO(2), but SO(2) in flue gas has a dual effect on the NO removal reaction.
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spelling pubmed-93866962022-08-19 Study on NO Removal Characteristics of the Fe(II)EDTA and Fe(II)PBTCA Composite System Ma, Liwei Li, Guoqiang Wang, Youqian Chai, Siqi Zhang, Guojie ACS Omega [Image: see text] Fe(2+) complexation wet denitrification technology has become a research hotspot. It is very important to achieve efficient regeneration of the absorbent and increase NO absorption in the Fe(2+) complexation system. They are the key to the industrial application of the Fe(2+) complexation absorption process. In this paper, 2-phosphonate-butane-1,2,4-tricarboxylic acid and ethylenediamine tetraacetic acid were used as ligands to prepare a composite system for the first time. The characteristics of NO removal were investigated under different temperatures, pHs, Fe(2+) concentrations, O(2) contents, NO concentrations, CO(2) contents, and SO(2) concentrations. Compared with the single ligand, the results show that the denitrification performance of the solution with a complex ligand is significantly improved. In this system, pH 9, 40 °C temperature, and 20 mmol/L Fe(2+) concentration are the economic ideal conditions for NO removal. The system can realize simultaneous removal of NO and SO(2), but SO(2) in flue gas has a dual effect on the NO removal reaction. American Chemical Society 2022-08-08 /pmc/articles/PMC9386696/ /pubmed/35990463 http://dx.doi.org/10.1021/acsomega.2c01641 Text en © 2022 The Authors. Published by American Chemical Society https://creativecommons.org/licenses/by-nc-nd/4.0/Permits non-commercial access and re-use, provided that author attribution and integrity are maintained; but does not permit creation of adaptations or other derivative works (https://creativecommons.org/licenses/by-nc-nd/4.0/).
spellingShingle Ma, Liwei
Li, Guoqiang
Wang, Youqian
Chai, Siqi
Zhang, Guojie
Study on NO Removal Characteristics of the Fe(II)EDTA and Fe(II)PBTCA Composite System
title Study on NO Removal Characteristics of the Fe(II)EDTA and Fe(II)PBTCA Composite System
title_full Study on NO Removal Characteristics of the Fe(II)EDTA and Fe(II)PBTCA Composite System
title_fullStr Study on NO Removal Characteristics of the Fe(II)EDTA and Fe(II)PBTCA Composite System
title_full_unstemmed Study on NO Removal Characteristics of the Fe(II)EDTA and Fe(II)PBTCA Composite System
title_short Study on NO Removal Characteristics of the Fe(II)EDTA and Fe(II)PBTCA Composite System
title_sort study on no removal characteristics of the fe(ii)edta and fe(ii)pbtca composite system
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9386696/
https://www.ncbi.nlm.nih.gov/pubmed/35990463
http://dx.doi.org/10.1021/acsomega.2c01641
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