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Customizing the Appearance of Sparks with Binary Metal Alloys

[Image: see text] Long-flying sparks are an essential part of several pyrotechnic effects. Unfortunately, and in contrast to colored flames, the color space of sparks is basically limited to the black body curve. With low-boiling-point metals, vapor-phase combustion and bright colorful flashes are a...

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Autores principales: Memmel, Philipp, Lederle, Felix, Söftje, Martin, Koch, Jannis, Li, Mingji, Schade, Wolfgang, Hübner, Eike G.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2022
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9386707/
https://www.ncbi.nlm.nih.gov/pubmed/35990440
http://dx.doi.org/10.1021/acsomega.2c03081
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author Memmel, Philipp
Lederle, Felix
Söftje, Martin
Koch, Jannis
Li, Mingji
Schade, Wolfgang
Hübner, Eike G.
author_facet Memmel, Philipp
Lederle, Felix
Söftje, Martin
Koch, Jannis
Li, Mingji
Schade, Wolfgang
Hübner, Eike G.
author_sort Memmel, Philipp
collection PubMed
description [Image: see text] Long-flying sparks are an essential part of several pyrotechnic effects. Unfortunately, and in contrast to colored flames, the color space of sparks is basically limited to the black body curve. With low-boiling-point metals, vapor-phase combustion and bright colorful flashes are achievable. Since 1999, alloys of rare-earth elements have been proposed for colorful spark generation. To the best of our knowledge, here, we present the first investigation of such alloys to change the color of sparks beyond the black body limit. Alloys consisting of >65 at. % of a brightly emitting and low-boiling-point metal and a carrier metal allow achieving long-flying deeply colored sparks. Besides the color, branching of sparks is crucial for the visual appearance. Rare-earth metals were found to promote branching of different alloys. Finally, fountains ejecting golden/green sparks based on a stable eutectic Yb–Cu alloy and continuously branching sparks based on Nd(2)Fe(14)B are presented.
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spelling pubmed-93867072022-08-19 Customizing the Appearance of Sparks with Binary Metal Alloys Memmel, Philipp Lederle, Felix Söftje, Martin Koch, Jannis Li, Mingji Schade, Wolfgang Hübner, Eike G. ACS Omega [Image: see text] Long-flying sparks are an essential part of several pyrotechnic effects. Unfortunately, and in contrast to colored flames, the color space of sparks is basically limited to the black body curve. With low-boiling-point metals, vapor-phase combustion and bright colorful flashes are achievable. Since 1999, alloys of rare-earth elements have been proposed for colorful spark generation. To the best of our knowledge, here, we present the first investigation of such alloys to change the color of sparks beyond the black body limit. Alloys consisting of >65 at. % of a brightly emitting and low-boiling-point metal and a carrier metal allow achieving long-flying deeply colored sparks. Besides the color, branching of sparks is crucial for the visual appearance. Rare-earth metals were found to promote branching of different alloys. Finally, fountains ejecting golden/green sparks based on a stable eutectic Yb–Cu alloy and continuously branching sparks based on Nd(2)Fe(14)B are presented. American Chemical Society 2022-08-01 /pmc/articles/PMC9386707/ /pubmed/35990440 http://dx.doi.org/10.1021/acsomega.2c03081 Text en © 2022 The Authors. Published by American Chemical Society https://creativecommons.org/licenses/by-nc-nd/4.0/Permits non-commercial access and re-use, provided that author attribution and integrity are maintained; but does not permit creation of adaptations or other derivative works (https://creativecommons.org/licenses/by-nc-nd/4.0/).
spellingShingle Memmel, Philipp
Lederle, Felix
Söftje, Martin
Koch, Jannis
Li, Mingji
Schade, Wolfgang
Hübner, Eike G.
Customizing the Appearance of Sparks with Binary Metal Alloys
title Customizing the Appearance of Sparks with Binary Metal Alloys
title_full Customizing the Appearance of Sparks with Binary Metal Alloys
title_fullStr Customizing the Appearance of Sparks with Binary Metal Alloys
title_full_unstemmed Customizing the Appearance of Sparks with Binary Metal Alloys
title_short Customizing the Appearance of Sparks with Binary Metal Alloys
title_sort customizing the appearance of sparks with binary metal alloys
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9386707/
https://www.ncbi.nlm.nih.gov/pubmed/35990440
http://dx.doi.org/10.1021/acsomega.2c03081
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