Coconut husk-raw clay-Fe composite: preparation, characteristics and mechanisms of Congo red adsorption

The release of unspent dyes from industries constitutes hazard and environmental challenges. For rapid and efficient removal of Congo red from aqueous solutions, a composite was prepared from coconut husk, raw clay, Fe(II) and Fe(II) compounds. Adsorption variables (initial pH of the solution, contact time, temperature and initial concentration of Congo red) were varied to understand the characteristics and mechanisms of the adsorption process. The composite was characterised using Fourier Transform Infrared (FTIR) spectroscopy, Scanning Electron Microscopy (SEM)–Energy dispersive X-ray (EDX) spectroscopy, nitrogen adsorption–desorption isotherm, X-ray Diffraction (XRD) spectroscopy and pH of the point zero charge (pH(pzc)). The optimal values of the pH, equilibrium time and temperature for adsorption of Congo red by the composite are 2, 40 min and 50 °C, respectively. The kinetic and equilibrium data followed Avrami fractional order and Langmuir models, respectively. A 1.0 g of the composite could maximally take up 1649.3 mg of Congo red at 50 °C. The values of ΔG° are in the range of − 27.901 to − 24.492 kJ mol(–1) while the value of ΔH° is − 72.239 kJ mol(–1). Hence, the removal of the Congo red by the composite was spontaneous, feasible and exothermic. The adsorption process was biphasic and followed physisorption process. Electrostatic interaction played a significant role in the removal of Congo red by the composite. The combine data in this study have proven that the clay composite, a cheap adsorbent, can be used for remediation of water contaminated with Congo red.