Mechanistic dichotomy in the solvent dependent access to E vs. Z-allylic amines via decarboxylative vinylation of amino acids

The solvent plays an important role in the photophysical properties of donor–acceptor based photocatalysts. The solvent-dependent access to E vs. Z-allylic amines was achieved via decarboxylative vinylation of amino acids with vinyl sulfones. Detailed experimental studies have been conducted to unde...

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Detalles Bibliográficos
Autores principales: Manna, Samir, Kakumachi, Shunta, Das, Kanak Kanti, Tsuchiya, Youichi, Adachi, Chihaya, Panda, Santanu
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2022
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9400591/
https://www.ncbi.nlm.nih.gov/pubmed/36091905
http://dx.doi.org/10.1039/d2sc02090d
Descripción
Sumario:The solvent plays an important role in the photophysical properties of donor–acceptor based photocatalysts. The solvent-dependent access to E vs. Z-allylic amines was achieved via decarboxylative vinylation of amino acids with vinyl sulfones. Detailed experimental studies have been conducted to understand the role of the solvent in the reactivity and stereoselectivity of the vinylation reactions.

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