Mechanistic dichotomy in the solvent dependent access to E vs. Z-allylic amines via decarboxylative vinylation of amino acids

The solvent plays an important role in the photophysical properties of donor–acceptor based photocatalysts. The solvent-dependent access to E vs. Z-allylic amines was achieved via decarboxylative vinylation of amino acids with vinyl sulfones. Detailed experimental studies have been conducted to unde...

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Detalles Bibliográficos
Autores principales: Manna, Samir, Kakumachi, Shunta, Das, Kanak Kanti, Tsuchiya, Youichi, Adachi, Chihaya, Panda, Santanu
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2022
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9400591/
https://www.ncbi.nlm.nih.gov/pubmed/36091905
http://dx.doi.org/10.1039/d2sc02090d
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author Manna, Samir
Kakumachi, Shunta
Das, Kanak Kanti
Tsuchiya, Youichi
Adachi, Chihaya
Panda, Santanu
author_facet Manna, Samir
Kakumachi, Shunta
Das, Kanak Kanti
Tsuchiya, Youichi
Adachi, Chihaya
Panda, Santanu
author_sort Manna, Samir
collection PubMed
description The solvent plays an important role in the photophysical properties of donor–acceptor based photocatalysts. The solvent-dependent access to E vs. Z-allylic amines was achieved via decarboxylative vinylation of amino acids with vinyl sulfones. Detailed experimental studies have been conducted to understand the role of the solvent in the reactivity and stereoselectivity of the vinylation reactions.
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spelling pubmed-94005912022-09-08 Mechanistic dichotomy in the solvent dependent access to E vs. Z-allylic amines via decarboxylative vinylation of amino acids Manna, Samir Kakumachi, Shunta Das, Kanak Kanti Tsuchiya, Youichi Adachi, Chihaya Panda, Santanu Chem Sci Chemistry The solvent plays an important role in the photophysical properties of donor–acceptor based photocatalysts. The solvent-dependent access to E vs. Z-allylic amines was achieved via decarboxylative vinylation of amino acids with vinyl sulfones. Detailed experimental studies have been conducted to understand the role of the solvent in the reactivity and stereoselectivity of the vinylation reactions. The Royal Society of Chemistry 2022-07-21 /pmc/articles/PMC9400591/ /pubmed/36091905 http://dx.doi.org/10.1039/d2sc02090d Text en This journal is © The Royal Society of Chemistry https://creativecommons.org/licenses/by-nc/3.0/
spellingShingle Chemistry
Manna, Samir
Kakumachi, Shunta
Das, Kanak Kanti
Tsuchiya, Youichi
Adachi, Chihaya
Panda, Santanu
Mechanistic dichotomy in the solvent dependent access to E vs. Z-allylic amines via decarboxylative vinylation of amino acids
title Mechanistic dichotomy in the solvent dependent access to E vs. Z-allylic amines via decarboxylative vinylation of amino acids
title_full Mechanistic dichotomy in the solvent dependent access to E vs. Z-allylic amines via decarboxylative vinylation of amino acids
title_fullStr Mechanistic dichotomy in the solvent dependent access to E vs. Z-allylic amines via decarboxylative vinylation of amino acids
title_full_unstemmed Mechanistic dichotomy in the solvent dependent access to E vs. Z-allylic amines via decarboxylative vinylation of amino acids
title_short Mechanistic dichotomy in the solvent dependent access to E vs. Z-allylic amines via decarboxylative vinylation of amino acids
title_sort mechanistic dichotomy in the solvent dependent access to e vs. z-allylic amines via decarboxylative vinylation of amino acids
topic Chemistry
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9400591/
https://www.ncbi.nlm.nih.gov/pubmed/36091905
http://dx.doi.org/10.1039/d2sc02090d
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