Towards Upcycling Biomass‐Derived Crosslinked Polymers with Light

Photodegradable, recyclable, and renewable, crosslinked polymers from bioresources show promise towards developing a sustainable strategy to address the issue of plastics degradability and recyclability. Photo processes are not widely exploited for upcycling polymers in spite of the potential to hav...

Descripción completa

Detalles Bibliográficos
Autores principales: Singathi, Ravichandranath, Raghunathan, Ramya, Krishnan, Retheesh, Kumar Rajendran, Saravana, Baburaj, Sruthy, Sibi, Mukund P., Webster, Dean C., Sivaguru, Jayaraman
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9400847/
https://www.ncbi.nlm.nih.gov/pubmed/35545813
http://dx.doi.org/10.1002/anie.202203353
_version_ 1784772832292503552
author Singathi, Ravichandranath
Raghunathan, Ramya
Krishnan, Retheesh
Kumar Rajendran, Saravana
Baburaj, Sruthy
Sibi, Mukund P.
Webster, Dean C.
Sivaguru, Jayaraman
author_facet Singathi, Ravichandranath
Raghunathan, Ramya
Krishnan, Retheesh
Kumar Rajendran, Saravana
Baburaj, Sruthy
Sibi, Mukund P.
Webster, Dean C.
Sivaguru, Jayaraman
author_sort Singathi, Ravichandranath
collection PubMed
description Photodegradable, recyclable, and renewable, crosslinked polymers from bioresources show promise towards developing a sustainable strategy to address the issue of plastics degradability and recyclability. Photo processes are not widely exploited for upcycling polymers in spite of the potential to have spatial and temporal control of the degradation in addition to being a green process. In this report we highlight a methodology in which biomass‐derived crosslinked polymers can be programmed to degrade at ≈300 nm with ≈60 % recovery of the monomer. The recovered monomer was recycled back to the crosslinked polymer.
format Online
Article
Text
id pubmed-9400847
institution National Center for Biotechnology Information
language English
publishDate 2022
publisher John Wiley and Sons Inc.
record_format MEDLINE/PubMed
spelling pubmed-94008472022-08-26 Towards Upcycling Biomass‐Derived Crosslinked Polymers with Light Singathi, Ravichandranath Raghunathan, Ramya Krishnan, Retheesh Kumar Rajendran, Saravana Baburaj, Sruthy Sibi, Mukund P. Webster, Dean C. Sivaguru, Jayaraman Angew Chem Int Ed Engl Communications Photodegradable, recyclable, and renewable, crosslinked polymers from bioresources show promise towards developing a sustainable strategy to address the issue of plastics degradability and recyclability. Photo processes are not widely exploited for upcycling polymers in spite of the potential to have spatial and temporal control of the degradation in addition to being a green process. In this report we highlight a methodology in which biomass‐derived crosslinked polymers can be programmed to degrade at ≈300 nm with ≈60 % recovery of the monomer. The recovered monomer was recycled back to the crosslinked polymer. John Wiley and Sons Inc. 2022-05-31 2022-08-01 /pmc/articles/PMC9400847/ /pubmed/35545813 http://dx.doi.org/10.1002/anie.202203353 Text en © 2022 The Authors. Angewandte Chemie International Edition published by Wiley-VCH GmbH https://creativecommons.org/licenses/by-nc-nd/4.0/This is an open access article under the terms of the http://creativecommons.org/licenses/by-nc-nd/4.0/ (https://creativecommons.org/licenses/by-nc-nd/4.0/) License, which permits use and distribution in any medium, provided the original work is properly cited, the use is non‐commercial and no modifications or adaptations are made.
spellingShingle Communications
Singathi, Ravichandranath
Raghunathan, Ramya
Krishnan, Retheesh
Kumar Rajendran, Saravana
Baburaj, Sruthy
Sibi, Mukund P.
Webster, Dean C.
Sivaguru, Jayaraman
Towards Upcycling Biomass‐Derived Crosslinked Polymers with Light
title Towards Upcycling Biomass‐Derived Crosslinked Polymers with Light
title_full Towards Upcycling Biomass‐Derived Crosslinked Polymers with Light
title_fullStr Towards Upcycling Biomass‐Derived Crosslinked Polymers with Light
title_full_unstemmed Towards Upcycling Biomass‐Derived Crosslinked Polymers with Light
title_short Towards Upcycling Biomass‐Derived Crosslinked Polymers with Light
title_sort towards upcycling biomass‐derived crosslinked polymers with light
topic Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9400847/
https://www.ncbi.nlm.nih.gov/pubmed/35545813
http://dx.doi.org/10.1002/anie.202203353
work_keys_str_mv AT singathiravichandranath towardsupcyclingbiomassderivedcrosslinkedpolymerswithlight
AT raghunathanramya towardsupcyclingbiomassderivedcrosslinkedpolymerswithlight
AT krishnanretheesh towardsupcyclingbiomassderivedcrosslinkedpolymerswithlight
AT kumarrajendransaravana towardsupcyclingbiomassderivedcrosslinkedpolymerswithlight
AT baburajsruthy towardsupcyclingbiomassderivedcrosslinkedpolymerswithlight
AT sibimukundp towardsupcyclingbiomassderivedcrosslinkedpolymerswithlight
AT websterdeanc towardsupcyclingbiomassderivedcrosslinkedpolymerswithlight
AT sivagurujayaraman towardsupcyclingbiomassderivedcrosslinkedpolymerswithlight

Ejemplares similares