Copper‐Catalyzed Borylation of Acyl Chlorides with an Alkoxy Diboron Reagent: A Facile Route to Acylboron Compounds

Herein, the copper‐catalyzed borylation of readily available acyl chlorides with bis(pinacolato)diboron, (B(2)pin(2)) or bis(neopentane glycolato)diboron (B(2)neop(2)) is reported, which provides stable potassium acyltrifluoroborates (KATs) in good yields from the acylboronate esters. A variety of f...

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Detalles Bibliográficos
Autores principales: Zhang, Xiaolei, Friedrich, Alexandra, Marder, Todd B.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Research Articles
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9400893/
https://www.ncbi.nlm.nih.gov/pubmed/35510606
http://dx.doi.org/10.1002/chem.202201329

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9400893/
https://www.ncbi.nlm.nih.gov/pubmed/35510606
http://dx.doi.org/10.1002/chem.202201329

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