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Selective [2+1+1] Fragmentation of P(4) by heteroleptic Metallasilylenes

Small‐molecule activation by low‐valent main‐group element compounds is of general interest. We here report the synthesis and characterization ((1)H, (13)C, (29)Si NMR, IR, sc‐XRD) of heteroleptic metallasilylenes L(1)(Cl)MSiL(2) (M=Al 1, Ga 2, L(1)=HC[C(Me)NDipp](2), Dipp=2,6‐( i )Pr(2)C(6)H(3); L(...

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Detalles Bibliográficos
Autores principales:	Schoening, Juliane, Gehlhaar, Alexander, Wölper, Christoph, Schulz, Stephan
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	John Wiley and Sons Inc. 2022
Materias:	Research Articles
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9400957/ https://www.ncbi.nlm.nih.gov/pubmed/35638137 http://dx.doi.org/10.1002/chem.202201031

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