A Silylene Stabilized by a σ‐Donating Nickel(0) Fragment

A donor‐stabilized silylene 4 featuring a Ni(0)‐based donating ligand was synthesized. Complex 4 exhibits a pyramidalized and nucleophilic Si(II) center and shows a peculiar behavior due to the cooperative reactivity of Si and Ni centers. Calculations indicate that the orientation of Ni‐ligands with...

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Detalles Bibliográficos
Autores principales: Frutos, María, Parvin, Nasrina, Baceiredo, Antoine, Madec, David, Saffon‐Merceron, Nathalie, Branchadell, Vicenç, Kato, Tsuyoshi
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9400971/
https://www.ncbi.nlm.nih.gov/pubmed/35510398
http://dx.doi.org/10.1002/anie.202201932

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9400971/
https://www.ncbi.nlm.nih.gov/pubmed/35510398
http://dx.doi.org/10.1002/anie.202201932

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