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Dissecting Solvent Effects on Hydrogen Bonding

The experimental isolation of H‐bond energetics from the typically dominant influence of the solvent remains challenging. Here we use synthetic molecular balances to quantify amine/amide H‐bonds in competitive solvents. Over 200 conformational free energy differences were determined using 24 H‐bondi...

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Detalles Bibliográficos
Autores principales:	Meredith, Nicole Y., Borsley, Stefan, Smolyar, Ivan V., Nichol, Gary S., Baker, Christopher M., Ling, Kenneth B., Cockroft, Scott L.
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	John Wiley and Sons Inc. 2022
Materias:	Communications
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9400978/ https://www.ncbi.nlm.nih.gov/pubmed/35608961 http://dx.doi.org/10.1002/anie.202206604

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