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Dissecting Solvent Effects on Hydrogen Bonding
The experimental isolation of H‐bond energetics from the typically dominant influence of the solvent remains challenging. Here we use synthetic molecular balances to quantify amine/amide H‐bonds in competitive solvents. Over 200 conformational free energy differences were determined using 24 H‐bondi...
Autores principales: | Meredith, Nicole Y., Borsley, Stefan, Smolyar, Ivan V., Nichol, Gary S., Baker, Christopher M., Ling, Kenneth B., Cockroft, Scott L. |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
John Wiley and Sons Inc.
2022
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9400978/ https://www.ncbi.nlm.nih.gov/pubmed/35608961 http://dx.doi.org/10.1002/anie.202206604 |
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