Metathesis between E−C(sp( n )) and H−C(sp(3)) σ‐Bonds (E=Si, Ge; n=2, 3) on an Osmium‐Polyhydride

The silylation of a phosphine of OsH(6)(P(i)Pr(3))(2) is performed via net‐metathesis between Si−C(sp( n )) and H−C(sp(3)) σ‐bonds (n=2, 3). Complex OsH(6)(P(i)Pr(3))(2) activates the Si−H bond of Et(3)SiH and Ph(3)SiH to give OsH(5)(SiR(3))(P(i)Pr(3))(2), which yield OsH(4){κ(1)‐P,η(2)‐SiH‐[(i)Pr(2...

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Detalles Bibliográficos
Autores principales: Esteruelas, Miguel A., López, Ana M., Oñate, Enrique, Raga, Esther
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Research Articles
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9401005/
https://www.ncbi.nlm.nih.gov/pubmed/35544362
http://dx.doi.org/10.1002/anie.202204081

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9401005/
https://www.ncbi.nlm.nih.gov/pubmed/35544362
http://dx.doi.org/10.1002/anie.202204081

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