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Metathesis between E−C(sp( n )) and H−C(sp(3)) σ‐Bonds (E=Si, Ge; n=2, 3) on an Osmium‐Polyhydride
The silylation of a phosphine of OsH(6)(P(i)Pr(3))(2) is performed via net‐metathesis between Si−C(sp( n )) and H−C(sp(3)) σ‐bonds (n=2, 3). Complex OsH(6)(P(i)Pr(3))(2) activates the Si−H bond of Et(3)SiH and Ph(3)SiH to give OsH(5)(SiR(3))(P(i)Pr(3))(2), which yield OsH(4){κ(1)‐P,η(2)‐SiH‐[(i)Pr(2...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
John Wiley and Sons Inc.
2022
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9401005/ https://www.ncbi.nlm.nih.gov/pubmed/35544362 http://dx.doi.org/10.1002/anie.202204081 |