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Crystalline Germanium(I) and Tin(I) Centered Radical Anions
An isostructural series of heavy Group 14 E(I) radical anions (Ge, Sn, Pb), stabilized by a bulky xanthene‐based diamido ligand are reported. The radical anions were synthesised by the one‐electron reduction of their corresponding E(II) precursor complexes with sodium naphthalenide in THF, yielding...
Autores principales: | , , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
John Wiley and Sons Inc.
2022
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9401049/ https://www.ncbi.nlm.nih.gov/pubmed/35266609 http://dx.doi.org/10.1002/anie.202201248 |