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Crystalline Germanium(I) and Tin(I) Centered Radical Anions

An isostructural series of heavy Group 14 E(I) radical anions (Ge, Sn, Pb), stabilized by a bulky xanthene‐based diamido ligand are reported. The radical anions were synthesised by the one‐electron reduction of their corresponding E(II) precursor complexes with sodium naphthalenide in THF, yielding...

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Detalles Bibliográficos
Autores principales: Lim, Li Feng, Judd, Martyna, Vasko, Petra, Gardiner, Michael G., Pantazis, Dimitrios A., Cox, Nicholas, Hicks, Jamie
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9401049/
https://www.ncbi.nlm.nih.gov/pubmed/35266609
http://dx.doi.org/10.1002/anie.202201248