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Synthesis and Characterization of Stable Iron Pentacarbonyl Radical Cation Salts
The open‐shell iron pentacarbonyl cation [Fe(CO)(5)](.+) was isolated by deelectronation, i.e., the single‐electron oxidation of the parent neutral Fe(CO)(5) using [phenazine(F)](.+) as the [Al(OR(F))(4)](−) and [F‐{Al(OR(F))(3)}(2)](−) salt (R(F)=C(CF(3))(3); phenazine(F)=perfluoro‐5,10‐bis(perfluo...
Autores principales: | Rall, Jan M., Schorpp, Marcel, Keilwerth, Martin, Mayländer, Maximilian, Friedmann, Christian, Daub, Michael, Richert, Sabine, Meyer, Karsten, Krossing, Ingo |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
John Wiley and Sons Inc.
2022
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9401057/ https://www.ncbi.nlm.nih.gov/pubmed/35543697 http://dx.doi.org/10.1002/anie.202204080 |
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