Cargando…

Organocatalytic Enantioselective Synthesis of Bicyclo[2.2.2]octenones via Oxaziridinium Catalysed ortho‐Hydroxylative Phenol Dearomatization

Hydroxylative dearomatization reactions of phenols (HPD) offer an efficient way to assemble complex, biologically relevant scaffolds. Despite this, enantioselective hydroxylative phenol dearomatizations for the construction of bicyclo[2.2.2]octenones are classically limited to stoichiometric chiral...

Descripción completa

Detalles Bibliográficos
Autores principales:	D'Arcy, Tom D., Elsegood, Mark R. J., Buckley, Benjamin R.
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	John Wiley and Sons Inc. 2022
Materias:	Communications
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9401573/ https://www.ncbi.nlm.nih.gov/pubmed/35543699 http://dx.doi.org/10.1002/anie.202205278

Ejemplares similares

Organocatalytic enantioselective dearomatization of thiophenes by 1,10-conjugate addition of indole imine methides
por: Li, Xingguang, et al.
Publicado: (2021)

Organocatalytic asymmetric chlorinative dearomatization of naphthols
por: Yin, Qin, et al.
Publicado: (2015)

Organocatalytic enantioselective conjugate addition of 2-naphthols to ortho-hydroxyphenyl substituted para-quinone methides: access to unsymmetrical triarylmethanes
por: Cheng, Yuyu, et al.
Publicado: (2019)

Catalytic asymmetric hydroxylative dearomatization of 2-naphthols: synthesis of lacinilene derivatives
por: Zhang, Yu, et al.
Publicado: (2017)

Biocatalytic site- and enantioselective oxidative dearomatization of phenols
por: Dockrey, Summer A. Baker, et al.
Publicado: (2017)

Tandem Dearomatization/Enantioselective Allylic Alkylation of Pyridines
por: Greßies, Steffen, et al.
Publicado: (2023)

(±)-trans-3-Benzoylbicyclo[2.2.2]octane-2-carboxylic acid
por: Lalancette, Roger A., et al.
Publicado: (2008)

Hypoiodite-Catalyzed Oxidative Umpolung of Indoles for Enantioselective Dearomatization
por: Tanaka, Hiroki, et al.
Publicado: (2022)

Enantioselective dearomatization reactions of heteroarenes by anion-binding organocatalysis
por: Aleksiev, Martin, et al.
Publicado: (2023)

Organocatalytic Asymmetric [2 + 4] Cycloadditions of 3-Vinylindoles with ortho-Quinone Methides
por: Liu, Si-Jia, et al.
Publicado: (2021)

The Attempted In Vivo Inhibition of the Ortho-hydroxylation of 2-Naphthylamine
por: Dewhurst, F.
Publicado: (1963)

Rhodium-catalysed ortho-alkynylation of nitroarenes
por: Tan, Eric, et al.
Publicado: (2021)

Photo-organocatalytic Enantioselective Perfluoroalkylation of β-Ketoesters
por: Woźniak, Łukasz, et al.
Publicado: (2015)

Synthesis and Properties of Octithiophene Dication Sterically Segregated by Annelation with Bicyclo[2.2.2]octene Units
por: Nishinaga, Tohru, et al.
Publicado: (2010)

Enantioselective N-heterocyclic carbene-catalyzed nucleophilic dearomatization of alkyl pyridiniums
por: Flanigan, Darrin M., et al.
Publicado: (2017)

Bicyclo[2.2.2]oct-7-ene-2,3,5,6-tetracarboxylic dianhydride
por: Hu, Tuoping
Publicado: (2008)

1-Cyanomethyl-4-aza-1-azoniabicyclo[2.2.2]octane bromide dihydrate
por: Cai, Ying
Publicado: (2010)

Benzene-1,3-diol–1,4-diazabicyclo[2.2.2]octane (1/1)
por: Arman, Hadi D., et al.
Publicado: (2010)

Light‐Driven Enantioselective Organocatalytic β‐Benzylation of Enals
por: Dell'Amico, Luca, et al.
Publicado: (2017)

Enantioselective Construction of Tertiary Fluoride Stereocenters by Organocatalytic Fluorocyclization
por: Wang, Qiang, et al.
Publicado: (2020)

Organocatalytic Enantioselective α-Bromination of Aldehydes with N-Bromosuccinimide
por: Hutchinson, George, et al.
Publicado: (2022)

Dimerization of confined Brønsted acids in enantioselective organocatalytic reactions
por: Harden, Ingolf, et al.
Publicado: (2023)

Organocatalytic Synthesis of α-Trifluoromethyl Allylboronic Acids by Enantioselective 1,2-Borotropic Migration
por: Jonker, Sybrand J. T., et al.
Publicado: (2020)

1-Methoxy-3-o-tolylbicyclo[2.2.2]oct-5-ene-2,2-dicarbonitrile
por: Büyükgüngör, Orhan, et al.
Publicado: (2009)

Photo‐Organocatalytic Enantioselective Radical Cascade Reactions of Unactivated Olefins
por: Bonilla, Pablo, et al.
Publicado: (2018)

Synthesis of Tetrasubstituted Nitroalkenes and Preliminary Studies of Their Enantioselective Organocatalytic Reduction
por: González, Patricia Camarero, et al.
Publicado: (2023)

Helical Multi‐Coordination Anion‐Binding Catalysts for the Highly Enantioselective Dearomatization of Pyrylium Derivatives
por: Fischer, Theresa, et al.
Publicado: (2018)

Enantioselective dearomatization of isoquinolines by anion-binding catalysis en route to cyclic α-aminophosphonates
por: Ray Choudhury, Abhijnan, et al.
Publicado: (2016)

1,4-Diazabicyclo[2.2.2]octane-1,4-diium bis(3-chlorobenzoate)
por: Yao, Zi-Shuo, et al.
Publicado: (2014)

Enantioselective organocatalytic Michael reactions using chiral (R,R)-1,2-diphenylethylenediamine-derived thioureas
por: Shim, Jae Ho, et al.
Publicado: (2020)

Enantioselective synthesis of 2-oxazolidinones by ruthenium(ii)–NHC-catalysed asymmetric hydrogenation of 2-oxazolones
por: Li, Wei, et al.
Publicado: (2018)

A General Organocatalytic System for Enantioselective Radical Conjugate Additions to Enals
por: Le Saux, Emilien, et al.
Publicado: (2021)

Silyldienolates in Organocatalytic Enantioselective Vinylogous Mukaiyama-Type Reactions: A Review
por: Hoppmann, Leon, et al.
Publicado: (2021)

Photochemical Organocatalytic Regio‐ and Enantioselective Conjugate Addition of Allyl Groups to Enals
por: Berger, Martin, et al.
Publicado: (2021)

Organocatalytic Enantioselective Michael Reaction of Aminomaleimides with Nitroolefins Catalyzed by Takemoto’s Catalyst
por: Mu, Hongwen, et al.
Publicado: (2022)

(1-Butyl-1,4-diazabicyclo[2.2.2]octon-1-ium-κN (4))trichloridocobalt(II)
por: Luachan, Sanchai, et al.
Publicado: (2009)

Crystal structure of bis(1,4-diazabicyclo[2.2.2]octan-1-ium) thiosulfate dihydrate
por: Seck, Gorgui Awa, et al.
Publicado: (2016)

Asymmetric 1,4-bis(ethynyl)bicyclo[2.2.2]octane rotators via monocarbinol functionalization. Ready access to polyrotors
por: Lemouchi, Cyprien, et al.
Publicado: (2015)

Influence of Ring Strain on the Formation of Rearrangement vs Cyclization Isotwistane Products in the Acyl Radical Reaction of Bicyclo[2.2.2]octanone
por: Chen, Chih-Ming, et al.
Publicado: (2023)

A tandem dearomatization/rearomatization strategy: enantioselective N-heterocyclic carbene-catalyzed α-arylation
por: Wu, Zijun, et al.
Publicado: (2018)

Cannot write session to /tmp/vufind_sessions/sess_8bj5k8uu0ge5o11r22j2jb7k57