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Metal‐Free Temperature‐Controlled Regiodivergent Borylative Cyclizations of Enynes: BCl(3)‐Promoted Skeletal Rearrangement
Metal‐free borylative cyclization of biphenyl‐embedded 1,3,5‐trien‐7‐ynes in the presence of simple and inexpensive BCl(3) provided synthetically useful borylated building blocks. The outcome of the process depends on the reaction temperature, with borylated phenanthrenes obtained at 60 °C and phena...
| Autores principales: | , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
John Wiley and Sons Inc.
2022
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9401584/ https://www.ncbi.nlm.nih.gov/pubmed/35510716 http://dx.doi.org/10.1002/anie.202205651 |