BIAN‐Aluminium‐Catalysed Imine Hydrogenation

Hydrogenations have been dominated by transition metal catalysis, while the use of more abundant and inexpensive main group metal catalysts has remained a great challenge. Here, a bimetallic Li/Al dihydride was successfully applied to catalytic hydrogenations of imines. The catalyst [((Dipp)BIAN)Al(...

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Autores principales: Pölker, Jennifer, Schaarschmidt, Dieter, Bernauer, Josef, Villa, Matteo, Jacobi von Wangelin, Axel
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Research Articles
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9401587/
https://www.ncbi.nlm.nih.gov/pubmed/36032039
http://dx.doi.org/10.1002/cctc.202200144
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author Pölker, Jennifer
Schaarschmidt, Dieter
Bernauer, Josef
Villa, Matteo
Jacobi von Wangelin, Axel
author_facet Pölker, Jennifer
Schaarschmidt, Dieter
Bernauer, Josef
Villa, Matteo
Jacobi von Wangelin, Axel
author_sort Pölker, Jennifer
collection PubMed
description Hydrogenations have been dominated by transition metal catalysis, while the use of more abundant and inexpensive main group metal catalysts has remained a great challenge. Here, a bimetallic Li/Al dihydride was successfully applied to catalytic hydrogenations of imines. The catalyst [((Dipp)BIAN)Al(μ‐H)(2)Li(OEt(2))(2)] was easily prepared from the 2e‐reduced BIAN derivative and LiAlH(4).
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spelling pubmed-94015872022-08-26 BIAN‐Aluminium‐Catalysed Imine Hydrogenation Pölker, Jennifer Schaarschmidt, Dieter Bernauer, Josef Villa, Matteo Jacobi von Wangelin, Axel ChemCatChem Research Articles Hydrogenations have been dominated by transition metal catalysis, while the use of more abundant and inexpensive main group metal catalysts has remained a great challenge. Here, a bimetallic Li/Al dihydride was successfully applied to catalytic hydrogenations of imines. The catalyst [((Dipp)BIAN)Al(μ‐H)(2)Li(OEt(2))(2)] was easily prepared from the 2e‐reduced BIAN derivative and LiAlH(4). John Wiley and Sons Inc. 2022-05-30 2022-08-05 /pmc/articles/PMC9401587/ /pubmed/36032039 http://dx.doi.org/10.1002/cctc.202200144 Text en © 2022 The Authors. ChemCatChem published by Wiley-VCH GmbH https://creativecommons.org/licenses/by-nc-nd/4.0/This is an open access article under the terms of the http://creativecommons.org/licenses/by-nc-nd/4.0/ (https://creativecommons.org/licenses/by-nc-nd/4.0/) License, which permits use and distribution in any medium, provided the original work is properly cited, the use is non‐commercial and no modifications or adaptations are made.
spellingShingle Research Articles
Pölker, Jennifer
Schaarschmidt, Dieter
Bernauer, Josef
Villa, Matteo
Jacobi von Wangelin, Axel
BIAN‐Aluminium‐Catalysed Imine Hydrogenation
title BIAN‐Aluminium‐Catalysed Imine Hydrogenation
title_full BIAN‐Aluminium‐Catalysed Imine Hydrogenation
title_fullStr BIAN‐Aluminium‐Catalysed Imine Hydrogenation
title_full_unstemmed BIAN‐Aluminium‐Catalysed Imine Hydrogenation
title_short BIAN‐Aluminium‐Catalysed Imine Hydrogenation
title_sort bian‐aluminium‐catalysed imine hydrogenation
topic Research Articles
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9401587/
https://www.ncbi.nlm.nih.gov/pubmed/36032039
http://dx.doi.org/10.1002/cctc.202200144
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AT schaarschmidtdieter bianaluminiumcatalysediminehydrogenation
AT bernauerjosef bianaluminiumcatalysediminehydrogenation
AT villamatteo bianaluminiumcatalysediminehydrogenation
AT jacobivonwangelinaxel bianaluminiumcatalysediminehydrogenation

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