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Fe(iii)-catalysed selective C–N bond cleavage of N-phenylamides by an electrochemical method

An Fe(iii)-catalysed transformation of secondary N-phenyl substituted amides to primary amides by an electrochemical method is developed. Regioselective aryl C–H oxygenation occurs during the reaction, promoting selective C(phenyl)-N bond cleavage to form primary amides in yields of up to 92%.

Detalles Bibliográficos
Autores principales: Xu, Yiwen, Long, Yang, Ye, Runyou, Li, Qiang, Ke, Fang, Zhou, Xiangge
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9403817/
https://www.ncbi.nlm.nih.gov/pubmed/36128521
http://dx.doi.org/10.1039/d2ra04709h

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