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Verification and Temperature-Dependent Rectification by HBQ, the Smallest Unimolecular Donor–Acceptor Rectifier
[Image: see text] Five years ago, rectification of electrical current was found in 4′-bromo-3,4-dicyano-2′,5′-dimethoxy-[1,1′-biphenyl]-2,5-dione (1), a hemibiquinone (which we will call either 1 or HBQ) that has a very small working length (1.1 nm). Monolayers of HBQ on Au(TS) were detected by “nan...
| Autores principales: | , , , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical Society
2022
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9404471/ https://www.ncbi.nlm.nih.gov/pubmed/36033727 http://dx.doi.org/10.1021/acsomega.2c01182 |