Activation of H–H, HO–H, C(sp(2))–H, C(sp(3))–H, and RO–H Bonds by Transition-Metal Frustrated Lewis Pairs Based on M/N (M = Rh, Ir) Couples

[Image: see text] Reaction of the dimers [(Cp*MCl)(2)(μ-Cl)(2)] (Cp* = η(5)-C(5)Me(5)) with Ph(2)PCH(2)CH(2)NC(NH(p-Tolyl))(2) (H(2)L) in the presence of NaSbF(6) affords the chlorido complexes [Cp*MCl(κ(2)N,P-H(2)L)][SbF(6)] (M = Rh, 1; Ir, 2). Upon treatment with aqueous NaOH, solutions of 1 and 2...

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Detalles Bibliográficos
Autores principales: Carmona, María, Pérez, Roberto, Ferrer, Joaquina, Rodríguez, Ricardo, Passarelli, Vincenzo, Lahoz, Fernando J., García-Orduña, Pilar, Carmona, Daniel
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2022
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9406284/
https://www.ncbi.nlm.nih.gov/pubmed/35948430
http://dx.doi.org/10.1021/acs.inorgchem.2c01902

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