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Mixed-Up-Ness or Entropy?

SIMPLE SUMMARY: The second law of thermodynamics has a mystical appeal in disciplines with tenuous connections to its origins. We hypothesize that many of these appeals instead should be to another principle heretofore unrecognized: the law of mixed-up-ness (LOM). Instead of using a number such as e...

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Autores principales: Seitz, W., Kirwan, A. D.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9407118/
https://www.ncbi.nlm.nih.gov/pubmed/36010754
http://dx.doi.org/10.3390/e24081090
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author Seitz, W.
Kirwan, A. D.
author_facet Seitz, W.
Kirwan, A. D.
author_sort Seitz, W.
collection PubMed
description SIMPLE SUMMARY: The second law of thermodynamics has a mystical appeal in disciplines with tenuous connections to its origins. We hypothesize that many of these appeals instead should be to another principle heretofore unrecognized: the law of mixed-up-ness (LOM). Instead of using a number such as entropy to characterize randomness, non-thermodynamic systems can be arranged in simple diagrams according to their degree of mixed-up-ness. Curiously, the evolution of such systems from degrees of low to high mixed-up-ness is both consistent with and richer than the principle of increasing entropy. ABSTRACT: Mixed-up-ness can be traced to unpublished notes by Josiah Gibbs. Subsequently, the concept was developed independently, and under somewhat different names, by other investigators. The central idea of mixed-up-ness is that systems states can be organized in a hierarchy by their degree of mixed-up-ness. In its purest form, the organizing principle is independent of thermodynamic and statistical mechanics principles, nor does it imply irreversibility. Yet, Gibbs and subsequent investigators kept entropy as the essential concept in determining system evolution, thus retaining the notion that systems evolve from states of perfect “order” to states of total “disorder”. Nevertheless, increasing mixed-up-ness is consistent with increasing entropy; however, there is no unique one-to-one connection between the two. We illustrate the notion of mixed-up-ness with an application to the permutation function of integer partitions and then formalize the notion of mixed-up-ness as a fundamental hierarchal principle, the law of mixed-up-ness (LOM), for non-thermodynamic systems.
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spelling pubmed-94071182022-08-26 Mixed-Up-Ness or Entropy? Seitz, W. Kirwan, A. D. Entropy (Basel) Article SIMPLE SUMMARY: The second law of thermodynamics has a mystical appeal in disciplines with tenuous connections to its origins. We hypothesize that many of these appeals instead should be to another principle heretofore unrecognized: the law of mixed-up-ness (LOM). Instead of using a number such as entropy to characterize randomness, non-thermodynamic systems can be arranged in simple diagrams according to their degree of mixed-up-ness. Curiously, the evolution of such systems from degrees of low to high mixed-up-ness is both consistent with and richer than the principle of increasing entropy. ABSTRACT: Mixed-up-ness can be traced to unpublished notes by Josiah Gibbs. Subsequently, the concept was developed independently, and under somewhat different names, by other investigators. The central idea of mixed-up-ness is that systems states can be organized in a hierarchy by their degree of mixed-up-ness. In its purest form, the organizing principle is independent of thermodynamic and statistical mechanics principles, nor does it imply irreversibility. Yet, Gibbs and subsequent investigators kept entropy as the essential concept in determining system evolution, thus retaining the notion that systems evolve from states of perfect “order” to states of total “disorder”. Nevertheless, increasing mixed-up-ness is consistent with increasing entropy; however, there is no unique one-to-one connection between the two. We illustrate the notion of mixed-up-ness with an application to the permutation function of integer partitions and then formalize the notion of mixed-up-ness as a fundamental hierarchal principle, the law of mixed-up-ness (LOM), for non-thermodynamic systems. MDPI 2022-08-08 /pmc/articles/PMC9407118/ /pubmed/36010754 http://dx.doi.org/10.3390/e24081090 Text en © 2022 by the authors. https://creativecommons.org/licenses/by/4.0/Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/).
spellingShingle Article
Seitz, W.
Kirwan, A. D.
Mixed-Up-Ness or Entropy?
title Mixed-Up-Ness or Entropy?
title_full Mixed-Up-Ness or Entropy?
title_fullStr Mixed-Up-Ness or Entropy?
title_full_unstemmed Mixed-Up-Ness or Entropy?
title_short Mixed-Up-Ness or Entropy?
title_sort mixed-up-ness or entropy?
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9407118/
https://www.ncbi.nlm.nih.gov/pubmed/36010754
http://dx.doi.org/10.3390/e24081090
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