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Improvement of Interfacial Adhesion and Thermomechanical Properties of PLA Based Composites with Wheat/Rice Bran

The present work aims to enhance the use of agricultural byproducts for the production of bio-composites by melt extrusion. It is well known that in the production of such bio-composites, the weak point is the filler-matrix interface, for this reason the adhesion between a polylactic acid (PLA)/poly...

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Autores principales: Gigante, Vito, Aliotta, Laura, Canesi, Ilaria, Sandroni, Marco, Lazzeri, Andrea, Coltelli, Maria-Beatrice, Cinelli, Patrizia
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9413742/
https://www.ncbi.nlm.nih.gov/pubmed/36015647
http://dx.doi.org/10.3390/polym14163389
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author Gigante, Vito
Aliotta, Laura
Canesi, Ilaria
Sandroni, Marco
Lazzeri, Andrea
Coltelli, Maria-Beatrice
Cinelli, Patrizia
author_facet Gigante, Vito
Aliotta, Laura
Canesi, Ilaria
Sandroni, Marco
Lazzeri, Andrea
Coltelli, Maria-Beatrice
Cinelli, Patrizia
author_sort Gigante, Vito
collection PubMed
description The present work aims to enhance the use of agricultural byproducts for the production of bio-composites by melt extrusion. It is well known that in the production of such bio-composites, the weak point is the filler-matrix interface, for this reason the adhesion between a polylactic acid (PLA)/poly(butylene succinate)(PBSA) blend and rice and wheat bran platelets was enhanced by a treatment method applied on the fillers using a suitable beeswax. Moreover, the coupling action of beeswax and inorganic fillers (such as talc and calcium carbonate) were investigated to improve the thermo-mechanical properties of the final composites. Through rheological (MFI), morphological (SEM), thermal (TGA, DSC), mechanical (Tensile, Impact), thermomechanical (HDT) characterizations and the application of analytical models, the optimum among the tested formulations was then selected.
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spelling pubmed-94137422022-08-27 Improvement of Interfacial Adhesion and Thermomechanical Properties of PLA Based Composites with Wheat/Rice Bran Gigante, Vito Aliotta, Laura Canesi, Ilaria Sandroni, Marco Lazzeri, Andrea Coltelli, Maria-Beatrice Cinelli, Patrizia Polymers (Basel) Article The present work aims to enhance the use of agricultural byproducts for the production of bio-composites by melt extrusion. It is well known that in the production of such bio-composites, the weak point is the filler-matrix interface, for this reason the adhesion between a polylactic acid (PLA)/poly(butylene succinate)(PBSA) blend and rice and wheat bran platelets was enhanced by a treatment method applied on the fillers using a suitable beeswax. Moreover, the coupling action of beeswax and inorganic fillers (such as talc and calcium carbonate) were investigated to improve the thermo-mechanical properties of the final composites. Through rheological (MFI), morphological (SEM), thermal (TGA, DSC), mechanical (Tensile, Impact), thermomechanical (HDT) characterizations and the application of analytical models, the optimum among the tested formulations was then selected. MDPI 2022-08-19 /pmc/articles/PMC9413742/ /pubmed/36015647 http://dx.doi.org/10.3390/polym14163389 Text en © 2022 by the authors. https://creativecommons.org/licenses/by/4.0/Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/).
spellingShingle Article
Gigante, Vito
Aliotta, Laura
Canesi, Ilaria
Sandroni, Marco
Lazzeri, Andrea
Coltelli, Maria-Beatrice
Cinelli, Patrizia
Improvement of Interfacial Adhesion and Thermomechanical Properties of PLA Based Composites with Wheat/Rice Bran
title Improvement of Interfacial Adhesion and Thermomechanical Properties of PLA Based Composites with Wheat/Rice Bran
title_full Improvement of Interfacial Adhesion and Thermomechanical Properties of PLA Based Composites with Wheat/Rice Bran
title_fullStr Improvement of Interfacial Adhesion and Thermomechanical Properties of PLA Based Composites with Wheat/Rice Bran
title_full_unstemmed Improvement of Interfacial Adhesion and Thermomechanical Properties of PLA Based Composites with Wheat/Rice Bran
title_short Improvement of Interfacial Adhesion and Thermomechanical Properties of PLA Based Composites with Wheat/Rice Bran
title_sort improvement of interfacial adhesion and thermomechanical properties of pla based composites with wheat/rice bran
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9413742/
https://www.ncbi.nlm.nih.gov/pubmed/36015647
http://dx.doi.org/10.3390/polym14163389
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