Two Magnetic Orderings and a Spin–Flop Transition in Mixed Valence Compound Mn(3)O(SeO(3))(3)

A mixed-valence manganese selenite, Mn(3)O(SeO(3))(3), was successfully synthesized using a conventional hydrothermal method. The three-dimensional framework of this compound is composed of an MnO(6) octahedra and an SeO(3) trigonal pyramid. The magnetic topological arrangement of manganese ions sho...

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Autores principales: Zhang, Wanwan, Cui, Meiyan, Tian, Jindou, Jiang, Pengfeng, Qian, Guoyu, Lu, Xia
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2022
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9414948/
https://www.ncbi.nlm.nih.gov/pubmed/36013909
http://dx.doi.org/10.3390/ma15165773
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author Zhang, Wanwan
Cui, Meiyan
Tian, Jindou
Jiang, Pengfeng
Qian, Guoyu
Lu, Xia
author_facet Zhang, Wanwan
Cui, Meiyan
Tian, Jindou
Jiang, Pengfeng
Qian, Guoyu
Lu, Xia
author_sort Zhang, Wanwan
collection PubMed
description A mixed-valence manganese selenite, Mn(3)O(SeO(3))(3), was successfully synthesized using a conventional hydrothermal method. The three-dimensional framework of this compound is composed of an MnO(6) octahedra and an SeO(3) trigonal pyramid. The magnetic topological arrangement of manganese ions shows a three-dimensional framework formed by the intersection of octa-kagomé spin sublattices and staircase-kagomé spin sublattices. Susceptibility, magnetization and heat capacity measurements confirm that Mn(3)O(SeO(3))(3) exhibits two successive long-range antiferromagnetic orderings with T(N1)~4.5 K and T(N2)~45 K and a field-induced spin–flop transition at a critical field of 4.5 T at low temperature.
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spelling pubmed-94149482022-08-27 Two Magnetic Orderings and a Spin–Flop Transition in Mixed Valence Compound Mn(3)O(SeO(3))(3) Zhang, Wanwan Cui, Meiyan Tian, Jindou Jiang, Pengfeng Qian, Guoyu Lu, Xia Materials (Basel) Article A mixed-valence manganese selenite, Mn(3)O(SeO(3))(3), was successfully synthesized using a conventional hydrothermal method. The three-dimensional framework of this compound is composed of an MnO(6) octahedra and an SeO(3) trigonal pyramid. The magnetic topological arrangement of manganese ions shows a three-dimensional framework formed by the intersection of octa-kagomé spin sublattices and staircase-kagomé spin sublattices. Susceptibility, magnetization and heat capacity measurements confirm that Mn(3)O(SeO(3))(3) exhibits two successive long-range antiferromagnetic orderings with T(N1)~4.5 K and T(N2)~45 K and a field-induced spin–flop transition at a critical field of 4.5 T at low temperature. MDPI 2022-08-21 /pmc/articles/PMC9414948/ /pubmed/36013909 http://dx.doi.org/10.3390/ma15165773 Text en © 2022 by the authors. https://creativecommons.org/licenses/by/4.0/Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/).
spellingShingle Article
Zhang, Wanwan
Cui, Meiyan
Tian, Jindou
Jiang, Pengfeng
Qian, Guoyu
Lu, Xia
Two Magnetic Orderings and a Spin–Flop Transition in Mixed Valence Compound Mn(3)O(SeO(3))(3)
title Two Magnetic Orderings and a Spin–Flop Transition in Mixed Valence Compound Mn(3)O(SeO(3))(3)
title_full Two Magnetic Orderings and a Spin–Flop Transition in Mixed Valence Compound Mn(3)O(SeO(3))(3)
title_fullStr Two Magnetic Orderings and a Spin–Flop Transition in Mixed Valence Compound Mn(3)O(SeO(3))(3)
title_full_unstemmed Two Magnetic Orderings and a Spin–Flop Transition in Mixed Valence Compound Mn(3)O(SeO(3))(3)
title_short Two Magnetic Orderings and a Spin–Flop Transition in Mixed Valence Compound Mn(3)O(SeO(3))(3)
title_sort two magnetic orderings and a spin–flop transition in mixed valence compound mn(3)o(seo(3))(3)
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9414948/
https://www.ncbi.nlm.nih.gov/pubmed/36013909
http://dx.doi.org/10.3390/ma15165773
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