Effect and Mechanism of Metakaolin Powder (MP) on Rheological and Mechanical Properties of Cementitious Suspension

The effects of metakaolin powder (MP) on the microscopic rheological properties and macroscopic flow parameters of cementitious suspension under various water–cement ratios were investigated. By analyzing the changes in the bonding strength coefficient and water film thickness (WFT), the mechanism of MP on flow and rheological parameters can be explored. Further, the effect of MP on mechanical properties was explained from the perspective of water absorption kinetics and hydration activity contribution rate. The incorporation of MP can reduce the flow rate and flow spread and increase the compressive strength, plastic viscosity, yield stress and thixotropy, and the effects of MP were distinctive under various W/CM ratios. The bonding strength coefficient and WFT increased and decreased with increasing MP replacement content, respectively. The regression analysis results revealed that the bonding strength coefficient and WFT were the most important factors influencing the macroscopic flow parameters and rheological parameters, which indicated that MP influenced the rheology and flowability of cementitious suspension by affecting the flocculent structure and particle distance. Compared with WFT, the bonding strength coefficient had a stronger effect on these parameters. The MP improved the compressive strength by reducing the average pore size and porosity and increasing the pore uniformity and hydration activity contribution rate of hardened paste, and this improvement was enhanced by increasing curing age.