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The Length Change Ratio of Ground Granulated Blast Furnace Slag-Based Geopolymer Blended with Magnesium Oxide Cured in Various Environments

Geopolymer (GP) has been considered a potential material to replace ordinary Portland cement (OPC) because of its excellent mechanical properties and environmentally friendly process. However, the promotion of GP is limited due to the large shrinkage and the different operating procedures compared t...

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Autores principales: Chen, Yen-Chun, Lee, Wei-Hao, Cheng, Ta-Wui, Chen, Walter, Li, Yeou-Fong
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9415670/
https://www.ncbi.nlm.nih.gov/pubmed/36015642
http://dx.doi.org/10.3390/polym14163386
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author Chen, Yen-Chun
Lee, Wei-Hao
Cheng, Ta-Wui
Chen, Walter
Li, Yeou-Fong
author_facet Chen, Yen-Chun
Lee, Wei-Hao
Cheng, Ta-Wui
Chen, Walter
Li, Yeou-Fong
author_sort Chen, Yen-Chun
collection PubMed
description Geopolymer (GP) has been considered a potential material to replace ordinary Portland cement (OPC) because of its excellent mechanical properties and environmentally friendly process. However, the promotion of GP is limited due to the large shrinkage and the different operating procedures compared to cement. This study aims to reduce the shrinkage of ground granulated blast furnace slag (GGBFS) based GP by the hydration expansion properties of activated magnesium oxide (MgO). The slurry of GP was blended from GGBFS, MgO, and activator; and the compositions of the activator are sodium hydroxide (NaOH), sodium silicate (Na(2)SiO(3)), and alumina silicate(NaAlO(2)). Herein, the GGFBS and MgO were a binder and a shrinkage compensation agent of GP, respectively. After unmolding, the GP specimens were cured under four types of environments and the lengths of the specimens were measured at different time intervals to understand the length change ratio of GP. In this study, two groups of GP specimens were made by fixing the activator to binder (A/B) ratio and the fluidity. The test results show that adding MgO will reduce the shrinkage of GP as A/B ratio was fixed. However, fixing the fluidity exhibited the opposite results. The X-ray diffraction (XRD) was used to check the Mg(OH)(2) that occurred due to the MgO hydration under four curing conditions. Three statistical and machine learning methods were used to analyze the length change of GP based on the test data. The testing and analysis results show that the influence of curing environments is more significant for improving the shrinkage of GP than additive MgO.
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spelling pubmed-94156702022-08-27 The Length Change Ratio of Ground Granulated Blast Furnace Slag-Based Geopolymer Blended with Magnesium Oxide Cured in Various Environments Chen, Yen-Chun Lee, Wei-Hao Cheng, Ta-Wui Chen, Walter Li, Yeou-Fong Polymers (Basel) Article Geopolymer (GP) has been considered a potential material to replace ordinary Portland cement (OPC) because of its excellent mechanical properties and environmentally friendly process. However, the promotion of GP is limited due to the large shrinkage and the different operating procedures compared to cement. This study aims to reduce the shrinkage of ground granulated blast furnace slag (GGBFS) based GP by the hydration expansion properties of activated magnesium oxide (MgO). The slurry of GP was blended from GGBFS, MgO, and activator; and the compositions of the activator are sodium hydroxide (NaOH), sodium silicate (Na(2)SiO(3)), and alumina silicate(NaAlO(2)). Herein, the GGFBS and MgO were a binder and a shrinkage compensation agent of GP, respectively. After unmolding, the GP specimens were cured under four types of environments and the lengths of the specimens were measured at different time intervals to understand the length change ratio of GP. In this study, two groups of GP specimens were made by fixing the activator to binder (A/B) ratio and the fluidity. The test results show that adding MgO will reduce the shrinkage of GP as A/B ratio was fixed. However, fixing the fluidity exhibited the opposite results. The X-ray diffraction (XRD) was used to check the Mg(OH)(2) that occurred due to the MgO hydration under four curing conditions. Three statistical and machine learning methods were used to analyze the length change of GP based on the test data. The testing and analysis results show that the influence of curing environments is more significant for improving the shrinkage of GP than additive MgO. MDPI 2022-08-18 /pmc/articles/PMC9415670/ /pubmed/36015642 http://dx.doi.org/10.3390/polym14163386 Text en © 2022 by the authors. https://creativecommons.org/licenses/by/4.0/Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/).
spellingShingle Article
Chen, Yen-Chun
Lee, Wei-Hao
Cheng, Ta-Wui
Chen, Walter
Li, Yeou-Fong
The Length Change Ratio of Ground Granulated Blast Furnace Slag-Based Geopolymer Blended with Magnesium Oxide Cured in Various Environments
title The Length Change Ratio of Ground Granulated Blast Furnace Slag-Based Geopolymer Blended with Magnesium Oxide Cured in Various Environments
title_full The Length Change Ratio of Ground Granulated Blast Furnace Slag-Based Geopolymer Blended with Magnesium Oxide Cured in Various Environments
title_fullStr The Length Change Ratio of Ground Granulated Blast Furnace Slag-Based Geopolymer Blended with Magnesium Oxide Cured in Various Environments
title_full_unstemmed The Length Change Ratio of Ground Granulated Blast Furnace Slag-Based Geopolymer Blended with Magnesium Oxide Cured in Various Environments
title_short The Length Change Ratio of Ground Granulated Blast Furnace Slag-Based Geopolymer Blended with Magnesium Oxide Cured in Various Environments
title_sort length change ratio of ground granulated blast furnace slag-based geopolymer blended with magnesium oxide cured in various environments
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9415670/
https://www.ncbi.nlm.nih.gov/pubmed/36015642
http://dx.doi.org/10.3390/polym14163386
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