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Adopting Sustainable Jatropha Oil Bio-Based Polymer Membranes as Alternatives for Environmental Remediation

This study aimed to optimize the removal of Cu(II) ions from an aqueous solution using a Jatropha oil bio-based membrane blended with 0.50 wt% graphene oxide (JPU/GO 0.50 wt%) using a central composite model (CCD) design using response surface methodology. The input factors were the feed concentrati...

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Autores principales: Harun, Nur Haninah, Zainal Abidin, Zurina, Majid, Umar Adam, Abdul Hamid, Mohamad Rezi, Abdullah, Abdul Halim, Othaman, Rizafizah, Harun, Mohd Yusof
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9416055/
https://www.ncbi.nlm.nih.gov/pubmed/36015582
http://dx.doi.org/10.3390/polym14163325
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author Harun, Nur Haninah
Zainal Abidin, Zurina
Majid, Umar Adam
Abdul Hamid, Mohamad Rezi
Abdullah, Abdul Halim
Othaman, Rizafizah
Harun, Mohd Yusof
author_facet Harun, Nur Haninah
Zainal Abidin, Zurina
Majid, Umar Adam
Abdul Hamid, Mohamad Rezi
Abdullah, Abdul Halim
Othaman, Rizafizah
Harun, Mohd Yusof
author_sort Harun, Nur Haninah
collection PubMed
description This study aimed to optimize the removal of Cu(II) ions from an aqueous solution using a Jatropha oil bio-based membrane blended with 0.50 wt% graphene oxide (JPU/GO 0.50 wt%) using a central composite model (CCD) design using response surface methodology. The input factors were the feed concentration (60–140) ppm, pressure (1.5–2.5) bar, and solution pH value (3–5). An optimum Cu(II) ions removal of 87% was predicted at 116 ppm feed concentration, 1.5 bar pressure, and pH 3.7, while the validated experimental result recorded 80% Cu(II) ions removal, with 95% of prediction intervals. A statistically non-significant term was removed from the analysis by the backward elimination method to improve the model’s accuracy. Using the reduction method, the predicted R(2) value was increased from −0.16 (−16%) to 0.88 (88%), suggesting that the reduced model had a good predictive ability. The quadratic regression model was significant (R(2) = 0.98) for the optimization prediction. Therefore, the results from the reduction model implied acceptable membrane performance, offering a better process optimization for Cu(II) ions removal.
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spelling pubmed-94160552022-08-27 Adopting Sustainable Jatropha Oil Bio-Based Polymer Membranes as Alternatives for Environmental Remediation Harun, Nur Haninah Zainal Abidin, Zurina Majid, Umar Adam Abdul Hamid, Mohamad Rezi Abdullah, Abdul Halim Othaman, Rizafizah Harun, Mohd Yusof Polymers (Basel) Article This study aimed to optimize the removal of Cu(II) ions from an aqueous solution using a Jatropha oil bio-based membrane blended with 0.50 wt% graphene oxide (JPU/GO 0.50 wt%) using a central composite model (CCD) design using response surface methodology. The input factors were the feed concentration (60–140) ppm, pressure (1.5–2.5) bar, and solution pH value (3–5). An optimum Cu(II) ions removal of 87% was predicted at 116 ppm feed concentration, 1.5 bar pressure, and pH 3.7, while the validated experimental result recorded 80% Cu(II) ions removal, with 95% of prediction intervals. A statistically non-significant term was removed from the analysis by the backward elimination method to improve the model’s accuracy. Using the reduction method, the predicted R(2) value was increased from −0.16 (−16%) to 0.88 (88%), suggesting that the reduced model had a good predictive ability. The quadratic regression model was significant (R(2) = 0.98) for the optimization prediction. Therefore, the results from the reduction model implied acceptable membrane performance, offering a better process optimization for Cu(II) ions removal. MDPI 2022-08-16 /pmc/articles/PMC9416055/ /pubmed/36015582 http://dx.doi.org/10.3390/polym14163325 Text en © 2022 by the authors. https://creativecommons.org/licenses/by/4.0/Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/).
spellingShingle Article
Harun, Nur Haninah
Zainal Abidin, Zurina
Majid, Umar Adam
Abdul Hamid, Mohamad Rezi
Abdullah, Abdul Halim
Othaman, Rizafizah
Harun, Mohd Yusof
Adopting Sustainable Jatropha Oil Bio-Based Polymer Membranes as Alternatives for Environmental Remediation
title Adopting Sustainable Jatropha Oil Bio-Based Polymer Membranes as Alternatives for Environmental Remediation
title_full Adopting Sustainable Jatropha Oil Bio-Based Polymer Membranes as Alternatives for Environmental Remediation
title_fullStr Adopting Sustainable Jatropha Oil Bio-Based Polymer Membranes as Alternatives for Environmental Remediation
title_full_unstemmed Adopting Sustainable Jatropha Oil Bio-Based Polymer Membranes as Alternatives for Environmental Remediation
title_short Adopting Sustainable Jatropha Oil Bio-Based Polymer Membranes as Alternatives for Environmental Remediation
title_sort adopting sustainable jatropha oil bio-based polymer membranes as alternatives for environmental remediation
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9416055/
https://www.ncbi.nlm.nih.gov/pubmed/36015582
http://dx.doi.org/10.3390/polym14163325
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