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One-pot synthesis of cobalt–rhenium nanoparticles taking the unusual β-Mn type structure
Using a facile one-pot colloidal method, it is now possible to obtain monodisperse Co(1−x)Re(x) nanoparticles (NPs), with excellent control of Re stoichiometry for x < 0.15. Re-incorporation in terms of a solid solution stabilizes the β-Mn polymorph relative to the hcp/ccp variants of cobalt. The...
Autores principales: | , , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
RSC
2020
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9417266/ https://www.ncbi.nlm.nih.gov/pubmed/36132513 http://dx.doi.org/10.1039/d0na00097c |
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author | Zacharaki, Eirini Bremmer, G. Marien Vajeeston, Ponniah Kalyva, Maria Fjellvåg, Helmer Kooyman, Patricia J. Sjåstad, Anja O. |
author_facet | Zacharaki, Eirini Bremmer, G. Marien Vajeeston, Ponniah Kalyva, Maria Fjellvåg, Helmer Kooyman, Patricia J. Sjåstad, Anja O. |
author_sort | Zacharaki, Eirini |
collection | PubMed |
description | Using a facile one-pot colloidal method, it is now possible to obtain monodisperse Co(1−x)Re(x) nanoparticles (NPs), with excellent control of Re stoichiometry for x < 0.15. Re-incorporation in terms of a solid solution stabilizes the β-Mn polymorph relative to the hcp/ccp variants of cobalt. The NPs are thermally stable up to 300 °C, which may make them attractive as model catalysts. |
format | Online Article Text |
id | pubmed-9417266 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2020 |
publisher | RSC |
record_format | MEDLINE/PubMed |
spelling | pubmed-94172662022-09-20 One-pot synthesis of cobalt–rhenium nanoparticles taking the unusual β-Mn type structure Zacharaki, Eirini Bremmer, G. Marien Vajeeston, Ponniah Kalyva, Maria Fjellvåg, Helmer Kooyman, Patricia J. Sjåstad, Anja O. Nanoscale Adv Chemistry Using a facile one-pot colloidal method, it is now possible to obtain monodisperse Co(1−x)Re(x) nanoparticles (NPs), with excellent control of Re stoichiometry for x < 0.15. Re-incorporation in terms of a solid solution stabilizes the β-Mn polymorph relative to the hcp/ccp variants of cobalt. The NPs are thermally stable up to 300 °C, which may make them attractive as model catalysts. RSC 2020-04-07 /pmc/articles/PMC9417266/ /pubmed/36132513 http://dx.doi.org/10.1039/d0na00097c Text en This journal is © The Royal Society of Chemistry https://creativecommons.org/licenses/by/3.0/ |
spellingShingle | Chemistry Zacharaki, Eirini Bremmer, G. Marien Vajeeston, Ponniah Kalyva, Maria Fjellvåg, Helmer Kooyman, Patricia J. Sjåstad, Anja O. One-pot synthesis of cobalt–rhenium nanoparticles taking the unusual β-Mn type structure |
title | One-pot synthesis of cobalt–rhenium nanoparticles taking the unusual β-Mn type structure |
title_full | One-pot synthesis of cobalt–rhenium nanoparticles taking the unusual β-Mn type structure |
title_fullStr | One-pot synthesis of cobalt–rhenium nanoparticles taking the unusual β-Mn type structure |
title_full_unstemmed | One-pot synthesis of cobalt–rhenium nanoparticles taking the unusual β-Mn type structure |
title_short | One-pot synthesis of cobalt–rhenium nanoparticles taking the unusual β-Mn type structure |
title_sort | one-pot synthesis of cobalt–rhenium nanoparticles taking the unusual β-mn type structure |
topic | Chemistry |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9417266/ https://www.ncbi.nlm.nih.gov/pubmed/36132513 http://dx.doi.org/10.1039/d0na00097c |
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