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Unveiling the interfacial electrochemiluminescence behavior of lead halide perovskite nanocrystals

In this study, a three-phase heterostructure interface including glassy carbon (conducting medium), CsPbBr(3) perovskite nanocrystals (PNCs, emitter) and acetonitrile (electrolyte) is constructed for fully investigating the interfacial electrochemiluminescence (ECL) behavior of CsPbBr(3) PNCs. We fi...

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Autores principales: Qiu, Linghang, Lin, Longhui, Huang, Yipeng, Lai, Zhiwei, Li, Feiming, Wang, Shuya, Lin, Fangyuan, Li, Jianfeng, Wang, Yiru, Chen, Xi
Formato: Online Artículo Texto
Lenguaje:English
Publicado: RSC 2019
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9417726/
https://www.ncbi.nlm.nih.gov/pubmed/36132118
http://dx.doi.org/10.1039/c9na00456d
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author Qiu, Linghang
Lin, Longhui
Huang, Yipeng
Lai, Zhiwei
Li, Feiming
Wang, Shuya
Lin, Fangyuan
Li, Jianfeng
Wang, Yiru
Chen, Xi
author_facet Qiu, Linghang
Lin, Longhui
Huang, Yipeng
Lai, Zhiwei
Li, Feiming
Wang, Shuya
Lin, Fangyuan
Li, Jianfeng
Wang, Yiru
Chen, Xi
author_sort Qiu, Linghang
collection PubMed
description In this study, a three-phase heterostructure interface including glassy carbon (conducting medium), CsPbBr(3) perovskite nanocrystals (PNCs, emitter) and acetonitrile (electrolyte) is constructed for fully investigating the interfacial electrochemiluminescence (ECL) behavior of CsPbBr(3) PNCs. We find that these interfaces serve as bridges for efficient electron–hole transfer during the ECL process. As a proof of concept, the increase of the heterostructure interface area will accordingly enhance the ECL intensity of CsPbBr(3) PNCs. About seven-fold enhancement of the ECL intensity could be achieved when the interface area has triple-fold increase, which provides a new perspective to construct more efficient ECL systems via interface engineering.
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spelling pubmed-94177262022-09-20 Unveiling the interfacial electrochemiluminescence behavior of lead halide perovskite nanocrystals Qiu, Linghang Lin, Longhui Huang, Yipeng Lai, Zhiwei Li, Feiming Wang, Shuya Lin, Fangyuan Li, Jianfeng Wang, Yiru Chen, Xi Nanoscale Adv Chemistry In this study, a three-phase heterostructure interface including glassy carbon (conducting medium), CsPbBr(3) perovskite nanocrystals (PNCs, emitter) and acetonitrile (electrolyte) is constructed for fully investigating the interfacial electrochemiluminescence (ECL) behavior of CsPbBr(3) PNCs. We find that these interfaces serve as bridges for efficient electron–hole transfer during the ECL process. As a proof of concept, the increase of the heterostructure interface area will accordingly enhance the ECL intensity of CsPbBr(3) PNCs. About seven-fold enhancement of the ECL intensity could be achieved when the interface area has triple-fold increase, which provides a new perspective to construct more efficient ECL systems via interface engineering. RSC 2019-09-03 /pmc/articles/PMC9417726/ /pubmed/36132118 http://dx.doi.org/10.1039/c9na00456d Text en This journal is © The Royal Society of Chemistry https://creativecommons.org/licenses/by/3.0/
spellingShingle Chemistry
Qiu, Linghang
Lin, Longhui
Huang, Yipeng
Lai, Zhiwei
Li, Feiming
Wang, Shuya
Lin, Fangyuan
Li, Jianfeng
Wang, Yiru
Chen, Xi
Unveiling the interfacial electrochemiluminescence behavior of lead halide perovskite nanocrystals
title Unveiling the interfacial electrochemiluminescence behavior of lead halide perovskite nanocrystals
title_full Unveiling the interfacial electrochemiluminescence behavior of lead halide perovskite nanocrystals
title_fullStr Unveiling the interfacial electrochemiluminescence behavior of lead halide perovskite nanocrystals
title_full_unstemmed Unveiling the interfacial electrochemiluminescence behavior of lead halide perovskite nanocrystals
title_short Unveiling the interfacial electrochemiluminescence behavior of lead halide perovskite nanocrystals
title_sort unveiling the interfacial electrochemiluminescence behavior of lead halide perovskite nanocrystals
topic Chemistry
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9417726/
https://www.ncbi.nlm.nih.gov/pubmed/36132118
http://dx.doi.org/10.1039/c9na00456d
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