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Diffusion doping of cobalt in rod-shape anatase TiO(2) nanocrystals leads to antiferromagnetism
Cobalt(ii) ions were adsorbed to the surface of rod-shape anatase TiO(2) nanocrystals and subsequently heated to promote ion diffusion into the nanocrystal. After removal of any remaining surface bound cobalt, a sample consisting of strictly cobalt-doped TiO(2) was obtained and characterized with po...
Autores principales: | , , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
RSC
2020
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9417846/ https://www.ncbi.nlm.nih.gov/pubmed/36132911 http://dx.doi.org/10.1039/d0na00640h |
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author | Mia, Shahzahan Varapragasam, Shelton J. P. Baride, Aravind Balasanthiran, Choumini Balasubramanian, Balamurugan Rioux, Robert M. Hoefelmeyer, James D. |
author_facet | Mia, Shahzahan Varapragasam, Shelton J. P. Baride, Aravind Balasanthiran, Choumini Balasubramanian, Balamurugan Rioux, Robert M. Hoefelmeyer, James D. |
author_sort | Mia, Shahzahan |
collection | PubMed |
description | Cobalt(ii) ions were adsorbed to the surface of rod-shape anatase TiO(2) nanocrystals and subsequently heated to promote ion diffusion into the nanocrystal. After removal of any remaining surface bound cobalt, a sample consisting of strictly cobalt-doped TiO(2) was obtained and characterized with powder X-ray diffraction, transmission electron microscopy, UV-visible spectroscopy, fluorescence spectroscopy, X-ray photoelectron spectroscopy, SQUID magnetometry, and inductively-coupled plasma atomic emission spectroscopy. The nanocrystal morphology was unchanged in the process and no new crystal phases were detected. The concentration of cobalt in the doped samples linearly correlates with the initial loading of cobalt(ii) ions on the nanocrystal surface. Thin films of the cobalt doped TiO(2) nanocrystals were prepared on indium-tin oxide coated glass substrate, and the electrical conductivity increased with the concentration of doped cobalt. Magnetic measurements of the cobalt-doped TiO(2) nanocrystals reveal paramagnetic behavior at room temperature, and antiferromagnetic interactions between Co ions at low temperatures. Antiferromagnetism is atypical for cobalt-doped TiO(2) nanocrystals, and is proposed to arise from interstitial doping that may be favored by the diffusional doping mechanism. |
format | Online Article Text |
id | pubmed-9417846 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2020 |
publisher | RSC |
record_format | MEDLINE/PubMed |
spelling | pubmed-94178462022-09-20 Diffusion doping of cobalt in rod-shape anatase TiO(2) nanocrystals leads to antiferromagnetism Mia, Shahzahan Varapragasam, Shelton J. P. Baride, Aravind Balasanthiran, Choumini Balasubramanian, Balamurugan Rioux, Robert M. Hoefelmeyer, James D. Nanoscale Adv Chemistry Cobalt(ii) ions were adsorbed to the surface of rod-shape anatase TiO(2) nanocrystals and subsequently heated to promote ion diffusion into the nanocrystal. After removal of any remaining surface bound cobalt, a sample consisting of strictly cobalt-doped TiO(2) was obtained and characterized with powder X-ray diffraction, transmission electron microscopy, UV-visible spectroscopy, fluorescence spectroscopy, X-ray photoelectron spectroscopy, SQUID magnetometry, and inductively-coupled plasma atomic emission spectroscopy. The nanocrystal morphology was unchanged in the process and no new crystal phases were detected. The concentration of cobalt in the doped samples linearly correlates with the initial loading of cobalt(ii) ions on the nanocrystal surface. Thin films of the cobalt doped TiO(2) nanocrystals were prepared on indium-tin oxide coated glass substrate, and the electrical conductivity increased with the concentration of doped cobalt. Magnetic measurements of the cobalt-doped TiO(2) nanocrystals reveal paramagnetic behavior at room temperature, and antiferromagnetic interactions between Co ions at low temperatures. Antiferromagnetism is atypical for cobalt-doped TiO(2) nanocrystals, and is proposed to arise from interstitial doping that may be favored by the diffusional doping mechanism. RSC 2020-09-09 /pmc/articles/PMC9417846/ /pubmed/36132911 http://dx.doi.org/10.1039/d0na00640h Text en This journal is © The Royal Society of Chemistry https://creativecommons.org/licenses/by-nc/3.0/ |
spellingShingle | Chemistry Mia, Shahzahan Varapragasam, Shelton J. P. Baride, Aravind Balasanthiran, Choumini Balasubramanian, Balamurugan Rioux, Robert M. Hoefelmeyer, James D. Diffusion doping of cobalt in rod-shape anatase TiO(2) nanocrystals leads to antiferromagnetism |
title | Diffusion doping of cobalt in rod-shape anatase TiO(2) nanocrystals leads to antiferromagnetism |
title_full | Diffusion doping of cobalt in rod-shape anatase TiO(2) nanocrystals leads to antiferromagnetism |
title_fullStr | Diffusion doping of cobalt in rod-shape anatase TiO(2) nanocrystals leads to antiferromagnetism |
title_full_unstemmed | Diffusion doping of cobalt in rod-shape anatase TiO(2) nanocrystals leads to antiferromagnetism |
title_short | Diffusion doping of cobalt in rod-shape anatase TiO(2) nanocrystals leads to antiferromagnetism |
title_sort | diffusion doping of cobalt in rod-shape anatase tio(2) nanocrystals leads to antiferromagnetism |
topic | Chemistry |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9417846/ https://www.ncbi.nlm.nih.gov/pubmed/36132911 http://dx.doi.org/10.1039/d0na00640h |
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