Preparation of SrTiO(3) nanocubes by CO(2) laser vaporization (LAVA) and hydrothermal maturation

SrTiO(3) is of particular interest for numerous applications such as photocatalytic water splitting, as an electrode material for thermoelectrics or as piezoceramics for sensors. Here we report on an advanced CO(2) laser vaporization (LAVA) method for the production of faceted, single-phase SrTiO(3) nanoparticles with an average particle size of 35 nm. Starting from a coarse SrTiO(3) raw powder, spherical SrTiO(3) nanoparticles were obtained by a laser-induced gas-phase condensation process. The composition of the nanoparticles corresponds to that of the starting powder, as XRD and FT-IR measurements show. Further hydrothermal treatment at 275 °C for 4 hours leads to the formation of faceted nanocubes with increasing crystallite size, as demonstrated by TEM, HR-TEM and XRD measurements. During a final washing step in 0.1 M HCl, SrCO(3) impurities were dissolved and thus single-phase SrTiO(3) nanocubes were successfully obtained, as shown by FT-IR, XRD and TEM analyses. The presented process facilitates the production of single-phase, highly crystalline SrTiO(3) nanopowders in sufficient quantities for subsequent use in a variety of applications, in particular for hydrogen production by photocatalytic water splitting.