Beam generation and structural optimization of size-selected Au(923) clusters

A size-selected beam of Au(923±20) clusters is generated in a gas-phase condensation cluster source equipped with a lateral time-of-flight mass selector. The beam current reaches up to 9.13 nA for small clusters and 80 pA for Au(923±20) clusters, which are then analyzed using a scanning transmission electron microscope. Four types of metastable structures are observed for the Au(923±20) clusters, including ino-decahedron (Dh), cuboctahedron and icosahedron (Ih). The proportion of bulk-favorable cuboctahedron (i.e. face center cubic (Fcc)) structure takes up only 10–20%, while the penta-rotating symmetrical structures (Dh/Ih) are the dominant ones which take up over three quarters. Changing the beam condition may optimize the clusters from Dh-dominant to the Ih-dominant phase, which paves the way towards nanoparticle control beyond the diameters.