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Biogenic synthesis of a green tea stabilized PPy/SWCNT/CdS nanocomposite and its substantial applications, photocatalytic degradation and rheological behavior

A green tea leaf-derived cadmium sulfide quantum dot-based system containing different weight percentages of single-walled carbon nanotubes (SWCNTs) and polypyrrole, named PSC, was designed via a green method. The photocatalytic degradation of Ponceau BS dye (λ(max) 505 nm) in the presence of PSC wa...

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Autores principales: Khan, Yashfeen, Ahmad, Anees, Ahmad, Nafees, Mir, Faraz Rasheed, Schories, Gerhard
Formato: Online Artículo Texto
Lenguaje:English
Publicado: RSC 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9419109/
https://www.ncbi.nlm.nih.gov/pubmed/36132303
http://dx.doi.org/10.1039/d0na00029a
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author Khan, Yashfeen
Ahmad, Anees
Ahmad, Nafees
Mir, Faraz Rasheed
Schories, Gerhard
author_facet Khan, Yashfeen
Ahmad, Anees
Ahmad, Nafees
Mir, Faraz Rasheed
Schories, Gerhard
author_sort Khan, Yashfeen
collection PubMed
description A green tea leaf-derived cadmium sulfide quantum dot-based system containing different weight percentages of single-walled carbon nanotubes (SWCNTs) and polypyrrole, named PSC, was designed via a green method. The photocatalytic degradation of Ponceau BS dye (λ(max) 505 nm) in the presence of PSC was measured. PSC with the highest weight percentage of SWCNTs (7-PSC) showed maximum photocatalytic activity, with 94.6% dye degradation in 55 minutes of irradiation time. This significant enhancement was due to the synergism in the intrinsic properties of the parent components. Alongside this, the rheological behavior of the prepared nanomaterial PSC was examined at constant (100 s(−1)) and varying shear rate from 0 to 500 s(−1) at a fixed temperature of 25 °C for a specified volume percentage of 0.1% using Castrol class: 15W-40 engine oil as a base fluid. The objective of lowering the viscosity of engine oil by 98.9% (initial: 0.221000 Pa s, final: 0.0022 Pa s.) was achieved by chartering/mixing the prepared PSC nanomaterial into the engine oil. A comparative study of the experimental and simulation outputs implied the high precision of the modeling via a neural network with minute 0.373 average % errors.
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spelling pubmed-94191092022-09-20 Biogenic synthesis of a green tea stabilized PPy/SWCNT/CdS nanocomposite and its substantial applications, photocatalytic degradation and rheological behavior Khan, Yashfeen Ahmad, Anees Ahmad, Nafees Mir, Faraz Rasheed Schories, Gerhard Nanoscale Adv Chemistry A green tea leaf-derived cadmium sulfide quantum dot-based system containing different weight percentages of single-walled carbon nanotubes (SWCNTs) and polypyrrole, named PSC, was designed via a green method. The photocatalytic degradation of Ponceau BS dye (λ(max) 505 nm) in the presence of PSC was measured. PSC with the highest weight percentage of SWCNTs (7-PSC) showed maximum photocatalytic activity, with 94.6% dye degradation in 55 minutes of irradiation time. This significant enhancement was due to the synergism in the intrinsic properties of the parent components. Alongside this, the rheological behavior of the prepared nanomaterial PSC was examined at constant (100 s(−1)) and varying shear rate from 0 to 500 s(−1) at a fixed temperature of 25 °C for a specified volume percentage of 0.1% using Castrol class: 15W-40 engine oil as a base fluid. The objective of lowering the viscosity of engine oil by 98.9% (initial: 0.221000 Pa s, final: 0.0022 Pa s.) was achieved by chartering/mixing the prepared PSC nanomaterial into the engine oil. A comparative study of the experimental and simulation outputs implied the high precision of the modeling via a neural network with minute 0.373 average % errors. RSC 2020-02-27 /pmc/articles/PMC9419109/ /pubmed/36132303 http://dx.doi.org/10.1039/d0na00029a Text en This journal is © The Royal Society of Chemistry https://creativecommons.org/licenses/by-nc/3.0/
spellingShingle Chemistry
Khan, Yashfeen
Ahmad, Anees
Ahmad, Nafees
Mir, Faraz Rasheed
Schories, Gerhard
Biogenic synthesis of a green tea stabilized PPy/SWCNT/CdS nanocomposite and its substantial applications, photocatalytic degradation and rheological behavior
title Biogenic synthesis of a green tea stabilized PPy/SWCNT/CdS nanocomposite and its substantial applications, photocatalytic degradation and rheological behavior
title_full Biogenic synthesis of a green tea stabilized PPy/SWCNT/CdS nanocomposite and its substantial applications, photocatalytic degradation and rheological behavior
title_fullStr Biogenic synthesis of a green tea stabilized PPy/SWCNT/CdS nanocomposite and its substantial applications, photocatalytic degradation and rheological behavior
title_full_unstemmed Biogenic synthesis of a green tea stabilized PPy/SWCNT/CdS nanocomposite and its substantial applications, photocatalytic degradation and rheological behavior
title_short Biogenic synthesis of a green tea stabilized PPy/SWCNT/CdS nanocomposite and its substantial applications, photocatalytic degradation and rheological behavior
title_sort biogenic synthesis of a green tea stabilized ppy/swcnt/cds nanocomposite and its substantial applications, photocatalytic degradation and rheological behavior
topic Chemistry
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9419109/
https://www.ncbi.nlm.nih.gov/pubmed/36132303
http://dx.doi.org/10.1039/d0na00029a
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