Control of the compositions and morphologies of uranium oxide nanocrystals in the solution phase: multi-monomer growth and self-catalysis

The presence of mixed products and impurities, which always confuse researchers, are common during synthesizing nanomaterials. Even though many studies have been conducted with an objective to control the synthesis of nanomaterials, very few studies have investigated a mechanism to control the composition of nanomaterials. Various products include UO(3)·H(2)O, U(3)O(8), UO(2), and U(4)O(9) were produced by simply adjusting the pH with ammonia. The morphology of UO(2) and U(3)O(8) are tunable. In this study, we suggest two mechanisms that can be used to control the nanomaterial composition. Various experiments have been conducted to understand the mechanism that controls the composition of nanomaterials. We indicate that a multi-monomer growth model can be used to control the uranium oxide composition. We have developed a new oxidation–reduction system using acetone, and this system is capable of controlling both the morphology and composition of uranium oxide micro/nanomaterials. Further, the presence of the self-catalysis mechanism can be used to regulate processes that control the monomer transformation. Thus, the results of this study can be applied to help in the construction of mixed-valence metal oxides.