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Grafting chelating groups on 2D carbon for selective heavy metal adsorption
Iminodiacetic acid (IDA) is a tridentate ligand, which can capture metal ions by forming two fused five-membered chelate rings. In this study, we fixed IDA moieties onto a two-dimensional nanocarbon, graphene oxide (GO), to obtain materials with high and selective adsorption of metal ions. The synth...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
RSC
2021
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9419290/ https://www.ncbi.nlm.nih.gov/pubmed/36132676 http://dx.doi.org/10.1039/d1na00435b |
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author | Shibahara, Risa Kamiya, Kazuhide Nishina, Yuta |
author_facet | Shibahara, Risa Kamiya, Kazuhide Nishina, Yuta |
author_sort | Shibahara, Risa |
collection | PubMed |
description | Iminodiacetic acid (IDA) is a tridentate ligand, which can capture metal ions by forming two fused five-membered chelate rings. In this study, we fixed IDA moieties onto a two-dimensional nanocarbon, graphene oxide (GO), to obtain materials with high and selective adsorption of metal ions. The synthesis conditions for the GO–IDA composites were optimized, then their structures were characterized by infrared spectroscopy (FT-IR), X-ray photoelectron spectroscopy (XPS), and CHN elemental analysis. In addition, the heavy-metal removal efficiency and selectivity of the GO–IDA composites with different length alkyl linkers between the GO and IDA were investigated. An aqueous solution containing 10 metal ions (Al, As, B, Cd, Cr, Cu, Mn, Pb, Se, and Zn) was used as a model for contaminated water at pH 7, and the interactions of the ions with GO–IDA were in the order of Cu > Pb > As > B > Zn > Al ≈ Se. The interaction between Cu and GO–IDA was confirmed by XPS and extended X-ray absorption fine structure (EXAFS), which showed that Cu was coordinated to IDA. |
format | Online Article Text |
id | pubmed-9419290 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2021 |
publisher | RSC |
record_format | MEDLINE/PubMed |
spelling | pubmed-94192902022-09-20 Grafting chelating groups on 2D carbon for selective heavy metal adsorption Shibahara, Risa Kamiya, Kazuhide Nishina, Yuta Nanoscale Adv Chemistry Iminodiacetic acid (IDA) is a tridentate ligand, which can capture metal ions by forming two fused five-membered chelate rings. In this study, we fixed IDA moieties onto a two-dimensional nanocarbon, graphene oxide (GO), to obtain materials with high and selective adsorption of metal ions. The synthesis conditions for the GO–IDA composites were optimized, then their structures were characterized by infrared spectroscopy (FT-IR), X-ray photoelectron spectroscopy (XPS), and CHN elemental analysis. In addition, the heavy-metal removal efficiency and selectivity of the GO–IDA composites with different length alkyl linkers between the GO and IDA were investigated. An aqueous solution containing 10 metal ions (Al, As, B, Cd, Cr, Cu, Mn, Pb, Se, and Zn) was used as a model for contaminated water at pH 7, and the interactions of the ions with GO–IDA were in the order of Cu > Pb > As > B > Zn > Al ≈ Se. The interaction between Cu and GO–IDA was confirmed by XPS and extended X-ray absorption fine structure (EXAFS), which showed that Cu was coordinated to IDA. RSC 2021-08-10 /pmc/articles/PMC9419290/ /pubmed/36132676 http://dx.doi.org/10.1039/d1na00435b Text en This journal is © The Royal Society of Chemistry https://creativecommons.org/licenses/by-nc/3.0/ |
spellingShingle | Chemistry Shibahara, Risa Kamiya, Kazuhide Nishina, Yuta Grafting chelating groups on 2D carbon for selective heavy metal adsorption |
title | Grafting chelating groups on 2D carbon for selective heavy metal adsorption |
title_full | Grafting chelating groups on 2D carbon for selective heavy metal adsorption |
title_fullStr | Grafting chelating groups on 2D carbon for selective heavy metal adsorption |
title_full_unstemmed | Grafting chelating groups on 2D carbon for selective heavy metal adsorption |
title_short | Grafting chelating groups on 2D carbon for selective heavy metal adsorption |
title_sort | grafting chelating groups on 2d carbon for selective heavy metal adsorption |
topic | Chemistry |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9419290/ https://www.ncbi.nlm.nih.gov/pubmed/36132676 http://dx.doi.org/10.1039/d1na00435b |
work_keys_str_mv | AT shibahararisa graftingchelatinggroupson2dcarbonforselectiveheavymetaladsorption AT kamiyakazuhide graftingchelatinggroupson2dcarbonforselectiveheavymetaladsorption AT nishinayuta graftingchelatinggroupson2dcarbonforselectiveheavymetaladsorption |