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Solvent-driven crystal–crystal transformation and morphology change in a 2D layered inorganic POM-based framework

In this paper, a pure 2D inorganic POM-based framework underwent a single crystal to single crystal conversion when soaked in organic solvents that are miscible with water, forming a more densely packed identical framework accompanying the formation of nanowires. The change in morphology is closely...

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Detalles Bibliográficos
Autores principales: Zeng, Hui-Min, Wang, Chao, Wu, Wei-Hong, Mao, Wei-Tao, Jiang, Zhan-Guo, Zhan, Cai-Hong
Formato: Online Artículo Texto
Lenguaje:English
Publicado: RSC 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9419534/
https://www.ncbi.nlm.nih.gov/pubmed/36134304
http://dx.doi.org/10.1039/d1na00416f
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author Zeng, Hui-Min
Wang, Chao
Wu, Wei-Hong
Mao, Wei-Tao
Jiang, Zhan-Guo
Zhan, Cai-Hong
author_facet Zeng, Hui-Min
Wang, Chao
Wu, Wei-Hong
Mao, Wei-Tao
Jiang, Zhan-Guo
Zhan, Cai-Hong
author_sort Zeng, Hui-Min
collection PubMed
description In this paper, a pure 2D inorganic POM-based framework underwent a single crystal to single crystal conversion when soaked in organic solvents that are miscible with water, forming a more densely packed identical framework accompanying the formation of nanowires. The change in morphology is closely related to the surface tension of water, and the lower surface tension achieved by dehydration promotes the formation of nanowires, which is revealed by SXRD, PXRD, SEM, TGA and electrochemical impedance spectroscopy (EIS).
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spelling pubmed-94195342022-09-20 Solvent-driven crystal–crystal transformation and morphology change in a 2D layered inorganic POM-based framework Zeng, Hui-Min Wang, Chao Wu, Wei-Hong Mao, Wei-Tao Jiang, Zhan-Guo Zhan, Cai-Hong Nanoscale Adv Chemistry In this paper, a pure 2D inorganic POM-based framework underwent a single crystal to single crystal conversion when soaked in organic solvents that are miscible with water, forming a more densely packed identical framework accompanying the formation of nanowires. The change in morphology is closely related to the surface tension of water, and the lower surface tension achieved by dehydration promotes the formation of nanowires, which is revealed by SXRD, PXRD, SEM, TGA and electrochemical impedance spectroscopy (EIS). RSC 2021-06-25 /pmc/articles/PMC9419534/ /pubmed/36134304 http://dx.doi.org/10.1039/d1na00416f Text en This journal is © The Royal Society of Chemistry https://creativecommons.org/licenses/by-nc/3.0/
spellingShingle Chemistry
Zeng, Hui-Min
Wang, Chao
Wu, Wei-Hong
Mao, Wei-Tao
Jiang, Zhan-Guo
Zhan, Cai-Hong
Solvent-driven crystal–crystal transformation and morphology change in a 2D layered inorganic POM-based framework
title Solvent-driven crystal–crystal transformation and morphology change in a 2D layered inorganic POM-based framework
title_full Solvent-driven crystal–crystal transformation and morphology change in a 2D layered inorganic POM-based framework
title_fullStr Solvent-driven crystal–crystal transformation and morphology change in a 2D layered inorganic POM-based framework
title_full_unstemmed Solvent-driven crystal–crystal transformation and morphology change in a 2D layered inorganic POM-based framework
title_short Solvent-driven crystal–crystal transformation and morphology change in a 2D layered inorganic POM-based framework
title_sort solvent-driven crystal–crystal transformation and morphology change in a 2d layered inorganic pom-based framework
topic Chemistry
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9419534/
https://www.ncbi.nlm.nih.gov/pubmed/36134304
http://dx.doi.org/10.1039/d1na00416f
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