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Facile fabrication of conductive MoS(2) thin films by sonication in hot water and evaluation of their electrocatalytic performance in the hydrogen evolution reaction
Molybdenum disulfide (MoS(2)) has long been used in catalysis and is a promising material for energy conversion devices. In order to utilize MoS(2) in electrocatalytic applications, it needs to be sufficiently conductive. Even though a metallic 1T phase of MoS(2) exists, its exfoliation process is e...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
RSC
2021
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9419535/ https://www.ncbi.nlm.nih.gov/pubmed/36132959 http://dx.doi.org/10.1039/d1na00456e |
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author | Saha, Dipankar Patel, Vinay Selvaganapathy, Ponnambalam Ravi Kruse, Peter |
author_facet | Saha, Dipankar Patel, Vinay Selvaganapathy, Ponnambalam Ravi Kruse, Peter |
author_sort | Saha, Dipankar |
collection | PubMed |
description | Molybdenum disulfide (MoS(2)) has long been used in catalysis and is a promising material for energy conversion devices. In order to utilize MoS(2) in electrocatalytic applications, it needs to be sufficiently conductive. Even though a metallic 1T phase of MoS(2) exists, its exfoliation process is expensive and difficult to scale because it involves hazardous materials and procedures, limiting its practical applications. We have previously reported an efficient and environmentally friendly procedure to exfoliate conductive MoS(2)via sonication in very dilute aqueous hydrogen peroxide. Here, we report a new way of exfoliating heavily doped conductive MoS(2) by sonication in pure water at 60 °C without additives. Conductivity measurements, Raman spectroscopy and X-ray photoelectron spectroscopy demonstrate that controlling the sonication time and temperature lead to the generation of small quantities of hydrogen peroxide in the water that interact with MoS(2) to form a small amount of sub-stoichiometric MoO(3−y). This impurity acts as a dopant and is responsible for the increase in conductivity of the MoS(2) films without compromising their structural integrity. We also evaluate the performance of the doped MoS(2) films as electrocatalysts in the hydrogen evolution reaction. We elucidate the mechanistic origin of the catalytic properties of these materials which may be of future use to develop a family of electrocatalysts based on doped MoS(2). |
format | Online Article Text |
id | pubmed-9419535 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2021 |
publisher | RSC |
record_format | MEDLINE/PubMed |
spelling | pubmed-94195352022-09-20 Facile fabrication of conductive MoS(2) thin films by sonication in hot water and evaluation of their electrocatalytic performance in the hydrogen evolution reaction Saha, Dipankar Patel, Vinay Selvaganapathy, Ponnambalam Ravi Kruse, Peter Nanoscale Adv Chemistry Molybdenum disulfide (MoS(2)) has long been used in catalysis and is a promising material for energy conversion devices. In order to utilize MoS(2) in electrocatalytic applications, it needs to be sufficiently conductive. Even though a metallic 1T phase of MoS(2) exists, its exfoliation process is expensive and difficult to scale because it involves hazardous materials and procedures, limiting its practical applications. We have previously reported an efficient and environmentally friendly procedure to exfoliate conductive MoS(2)via sonication in very dilute aqueous hydrogen peroxide. Here, we report a new way of exfoliating heavily doped conductive MoS(2) by sonication in pure water at 60 °C without additives. Conductivity measurements, Raman spectroscopy and X-ray photoelectron spectroscopy demonstrate that controlling the sonication time and temperature lead to the generation of small quantities of hydrogen peroxide in the water that interact with MoS(2) to form a small amount of sub-stoichiometric MoO(3−y). This impurity acts as a dopant and is responsible for the increase in conductivity of the MoS(2) films without compromising their structural integrity. We also evaluate the performance of the doped MoS(2) films as electrocatalysts in the hydrogen evolution reaction. We elucidate the mechanistic origin of the catalytic properties of these materials which may be of future use to develop a family of electrocatalysts based on doped MoS(2). RSC 2021-10-29 /pmc/articles/PMC9419535/ /pubmed/36132959 http://dx.doi.org/10.1039/d1na00456e Text en This journal is © The Royal Society of Chemistry https://creativecommons.org/licenses/by-nc/3.0/ |
spellingShingle | Chemistry Saha, Dipankar Patel, Vinay Selvaganapathy, Ponnambalam Ravi Kruse, Peter Facile fabrication of conductive MoS(2) thin films by sonication in hot water and evaluation of their electrocatalytic performance in the hydrogen evolution reaction |
title | Facile fabrication of conductive MoS(2) thin films by sonication in hot water and evaluation of their electrocatalytic performance in the hydrogen evolution reaction |
title_full | Facile fabrication of conductive MoS(2) thin films by sonication in hot water and evaluation of their electrocatalytic performance in the hydrogen evolution reaction |
title_fullStr | Facile fabrication of conductive MoS(2) thin films by sonication in hot water and evaluation of their electrocatalytic performance in the hydrogen evolution reaction |
title_full_unstemmed | Facile fabrication of conductive MoS(2) thin films by sonication in hot water and evaluation of their electrocatalytic performance in the hydrogen evolution reaction |
title_short | Facile fabrication of conductive MoS(2) thin films by sonication in hot water and evaluation of their electrocatalytic performance in the hydrogen evolution reaction |
title_sort | facile fabrication of conductive mos(2) thin films by sonication in hot water and evaluation of their electrocatalytic performance in the hydrogen evolution reaction |
topic | Chemistry |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9419535/ https://www.ncbi.nlm.nih.gov/pubmed/36132959 http://dx.doi.org/10.1039/d1na00456e |
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