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Designing Zinc Deposition Substrate with Fully Preferred Orientation to Elude the Interfacial Inhomogeneous Dendrite Growth

The development of zinc-ion batteries with high energy density remains a great challenge due to the uncontrollable dendrite growth on their zinc metal anodes. Film anodes plated on the substrate have attracted increasing attention to alleviate these dendrite issues. Herein, we first point out that b...

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Autores principales: Xie, Chunlin, Yang, Zefang, Zhang, Qi, Ji, Huimin, Li, Yihu, Wu, Tingqing, Li, Wenbin, Wu, Pengfei, Wang, Haiyan
Formato: Online Artículo Texto
Lenguaje:English
Publicado: AAAS 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9422332/
https://www.ncbi.nlm.nih.gov/pubmed/36072269
http://dx.doi.org/10.34133/2022/9841343
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author Xie, Chunlin
Yang, Zefang
Zhang, Qi
Ji, Huimin
Li, Yihu
Wu, Tingqing
Li, Wenbin
Wu, Pengfei
Wang, Haiyan
author_facet Xie, Chunlin
Yang, Zefang
Zhang, Qi
Ji, Huimin
Li, Yihu
Wu, Tingqing
Li, Wenbin
Wu, Pengfei
Wang, Haiyan
author_sort Xie, Chunlin
collection PubMed
description The development of zinc-ion batteries with high energy density remains a great challenge due to the uncontrollable dendrite growth on their zinc metal anodes. Film anodes plated on the substrate have attracted increasing attention to alleviate these dendrite issues. Herein, we first point out that both the random crystal orientation and the low metal affinity of the substrate are important factors of zinc dendrite formation. Accordingly, the (1 0 1) fully preferred tin interface layer with high zinc affinity was fabricated by chemical tin plating on (1 0 0) oriented copper. This tin decorated copper substrate can realize high reversible zinc plating/stripping behavior, and full cell using this zinc plated substrate can be operated for more than 1000 cycles with high capacity retention (85.3%) and low electrochemical impedance. The proposed strategy can be also applied to lithium metal batteries, which demonstrates that the substrate orientation regulation and metal affinity design are the promising approaches to achieve dendrite-free metal anode and overcome the challenges of highly reactive metal anodes.
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spelling pubmed-94223322022-09-06 Designing Zinc Deposition Substrate with Fully Preferred Orientation to Elude the Interfacial Inhomogeneous Dendrite Growth Xie, Chunlin Yang, Zefang Zhang, Qi Ji, Huimin Li, Yihu Wu, Tingqing Li, Wenbin Wu, Pengfei Wang, Haiyan Research (Wash D C) Research Article The development of zinc-ion batteries with high energy density remains a great challenge due to the uncontrollable dendrite growth on their zinc metal anodes. Film anodes plated on the substrate have attracted increasing attention to alleviate these dendrite issues. Herein, we first point out that both the random crystal orientation and the low metal affinity of the substrate are important factors of zinc dendrite formation. Accordingly, the (1 0 1) fully preferred tin interface layer with high zinc affinity was fabricated by chemical tin plating on (1 0 0) oriented copper. This tin decorated copper substrate can realize high reversible zinc plating/stripping behavior, and full cell using this zinc plated substrate can be operated for more than 1000 cycles with high capacity retention (85.3%) and low electrochemical impedance. The proposed strategy can be also applied to lithium metal batteries, which demonstrates that the substrate orientation regulation and metal affinity design are the promising approaches to achieve dendrite-free metal anode and overcome the challenges of highly reactive metal anodes. AAAS 2022-08-18 /pmc/articles/PMC9422332/ /pubmed/36072269 http://dx.doi.org/10.34133/2022/9841343 Text en Copyright © 2022 Chunlin Xie et al. https://creativecommons.org/licenses/by/4.0/Exclusive Licensee Science and Technology Review Publishing House. Distributed under a Creative Commons Attribution License (CC BY 4.0).
spellingShingle Research Article
Xie, Chunlin
Yang, Zefang
Zhang, Qi
Ji, Huimin
Li, Yihu
Wu, Tingqing
Li, Wenbin
Wu, Pengfei
Wang, Haiyan
Designing Zinc Deposition Substrate with Fully Preferred Orientation to Elude the Interfacial Inhomogeneous Dendrite Growth
title Designing Zinc Deposition Substrate with Fully Preferred Orientation to Elude the Interfacial Inhomogeneous Dendrite Growth
title_full Designing Zinc Deposition Substrate with Fully Preferred Orientation to Elude the Interfacial Inhomogeneous Dendrite Growth
title_fullStr Designing Zinc Deposition Substrate with Fully Preferred Orientation to Elude the Interfacial Inhomogeneous Dendrite Growth
title_full_unstemmed Designing Zinc Deposition Substrate with Fully Preferred Orientation to Elude the Interfacial Inhomogeneous Dendrite Growth
title_short Designing Zinc Deposition Substrate with Fully Preferred Orientation to Elude the Interfacial Inhomogeneous Dendrite Growth
title_sort designing zinc deposition substrate with fully preferred orientation to elude the interfacial inhomogeneous dendrite growth
topic Research Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9422332/
https://www.ncbi.nlm.nih.gov/pubmed/36072269
http://dx.doi.org/10.34133/2022/9841343
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