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Precursor engineering of hydrotalcite-derived redox sorbents for reversible and stable thermochemical oxygen storage

Chemical looping processes based on multiple-step reduction and oxidation of metal oxides hold great promise for a variety of energy applications, such as CO(2) capture and conversion, gas separation, energy storage, and redox catalytic processes. Copper-based mixed oxides are one of the most promis...

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Detalles Bibliográficos
Autores principales: High, Michael, Patzschke, Clemens F., Zheng, Liya, Zeng, Dewang, Gavalda-Diaz, Oriol, Ding, Nan, Chien, Ka Ho Horace, Zhang, Zili, Wilson, George E., Berenov, Andrey V., Skinner, Stephen J., Sedransk Campbell, Kyra L., Xiao, Rui, Fennell, Paul S., Song, Qilei
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9427752/
https://www.ncbi.nlm.nih.gov/pubmed/36042227
http://dx.doi.org/10.1038/s41467-022-32593-6
Descripción
Sumario:Chemical looping processes based on multiple-step reduction and oxidation of metal oxides hold great promise for a variety of energy applications, such as CO(2) capture and conversion, gas separation, energy storage, and redox catalytic processes. Copper-based mixed oxides are one of the most promising candidate materials with a high oxygen storage capacity. However, the structural deterioration and sintering at high temperatures is one key scientific challenge. Herein, we report a precursor engineering approach to prepare durable copper-based redox sorbents for use in thermochemical looping processes for combustion and gas purification. Calcination of the CuMgAl hydrotalcite precursors formed mixed metal oxides consisting of CuO nanoparticles dispersed in the Mg-Al oxide support which inhibited the formation of copper aluminates during redox cycling. The copper-based redox sorbents demonstrated enhanced reaction rates, stable O(2) storage capacity over 500 redox cycles at 900 °C, and efficient gas purification over a broad temperature range. We expect that our materials design strategy has broad implications on synthesis and engineering of mixed metal oxides for a range of thermochemical processes and redox catalytic applications.